Heteronuclear RuIIAgI complexes having a pyrroloquinolinequinone derivative as a bridging ligand

Hiroumi Mitome, Tomoya Ishizuka, Yoshihito Shiota, Kazunari Yoshizawa, Takahiko Kojima

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

Herein, we report the synthesis of a novel heterohexanuclear complex (1) of a heteroaromatic cofactor, pyrroloquinolinequinone (PQQ). The crystal structure of 1 was determined to reveal that two PQQ-bridged RuIIAg I units were linked by two [AgI(OTf)2] - units (OTf = CF3SO3 -). A solvent-bound RuIIAgI heterodinuclear complex (2) was formed from 1 in a coordinating solvent such as acetone to show an intense metal-to-ligand charge-transfer band at 709 nm.

Original languageEnglish
Pages (from-to)2274-2276
Number of pages3
JournalInorganic Chemistry
Volume52
Issue number5
DOIs
Publication statusPublished - Mar 11 2013

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Ligands
Derivatives
ligands
Acetone
acetone
Charge transfer
Crystal structure
Metals
charge transfer
crystal structure
synthesis
metals

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Cite this

Heteronuclear RuIIAgI complexes having a pyrroloquinolinequinone derivative as a bridging ligand. / Mitome, Hiroumi; Ishizuka, Tomoya; Shiota, Yoshihito; Yoshizawa, Kazunari; Kojima, Takahiko.

In: Inorganic Chemistry, Vol. 52, No. 5, 11.03.2013, p. 2274-2276.

Research output: Contribution to journalArticle

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AU - Yoshizawa, Kazunari

AU - Kojima, Takahiko

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