Hexafluoro complex of rutherfordium in mixed HF/HNO3 solutions

A. Toyoshima, H. Haba, K. Tsukada, M. Asai, K. Akiyama, S. Goto, Y. Ishii, I. Nishinaka, T. K. Sato, Y. Nagame, W. Sato, Y. Tani, H. Hasegawa, K. Matsuo, D. Saika, Y. Kitamoto, A. Shinohara, M. Ito, J. Saito, H. KudoA. Yokoyama, M. Sakama, K. Sueki, Y. Oura, H. Nakahara, M. Schädel, W. Brüchle, J. V. Kratz

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32 Citations (Scopus)

Abstract

Formation of anionic fluoride-complexes of element 104, rutherfordium, produced in the 248Cm(18O, 5n)261Rf reaction was studied by anion-exchange on an atom-at-a-time scale. It was found that the hexafluoro complex of Rf, [RfF6]2-, was formed in the studied fluoride ion concentrations of 0.0005-0.013 M. Formation of [RfF 6]2- was significantly different from that of the homologues Zr and Hf, [ZrF6]2- and [HfF6] 2-; the evaluated formation constant of [RfF6] 2- is at least one-order of magnitude smaller than those of [ZrF 6]2- and [HfF6]2-.

Original languageEnglish
Pages (from-to)125-134
Number of pages10
JournalRadiochimica Acta
Volume96
Issue number3
DOIs
Publication statusPublished - 2008
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry

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