Hexapalladium cluster: Unique cluster construction reaction of cyclic Pd3(CNC6H3Me2-2,6) 6 and linear [Pd3(CNC6H3Me2-2,6) 8]2+

Masato Ohashi, Jianjun Yi, Daisuke Shimizu, Tsuneaki Yamagata, Takashi Ohshima, Kazushi Mashima

Research output: Contribution to journalArticlepeer-review

6 Citations (Scopus)

Abstract

Reaction of a triangle Pd(0) complex, Pd3(CNXyl)6 (1; Xyl = 2,6-C6H3Me2), with a dicationic linear trinuclear complex [Pd3(CNXyl)8][PF6]2 (3) afforded a dicationic hexapalladium complex [Pd6(CNXyl)12][PF6]2 (4), while the reaction of 1 with a dicationic dinuclear complex [Pd2(CNXyl)6][PF6]2 (2) resulted in the formation of 3. The molecular structure of the complex 4 was determined by X-ray crystallography and spectroscopic analysis.

Original languageEnglish
Pages (from-to)2457-2464
Number of pages8
JournalJournal of Organometallic Chemistry
Volume691
Issue number11
DOIs
Publication statusPublished - May 15 2006
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Fingerprint Dive into the research topics of 'Hexapalladium cluster: Unique cluster construction reaction of cyclic Pd<sub>3</sub>(CNC<sub>6</sub>H<sub>3</sub>Me<sub>2</sub>-2,6) <sub>6</sub> and linear [Pd<sub>3</sub>(CNC<sub>6</sub>H<sub>3</sub>Me<sub>2</sub>-2,6) <sub>8</sub>]<sup>2+</sup>'. Together they form a unique fingerprint.

Cite this