Hexapalladium cluster: Unique cluster construction reaction of cyclic Pd3(CNC6H3Me2-2,6) 6 and linear [Pd3(CNC6H3Me2-2,6) 8]2+

Masato Ohashi, Jianjun Yi, Daisuke Shimizu, Tsuneaki Yamagata, Takashi Ohshima, Kazushi Mashima

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Reaction of a triangle Pd(0) complex, Pd3(CNXyl)6 (1; Xyl = 2,6-C6H3Me2), with a dicationic linear trinuclear complex [Pd3(CNXyl)8][PF6]2 (3) afforded a dicationic hexapalladium complex [Pd6(CNXyl)12][PF6]2 (4), while the reaction of 1 with a dicationic dinuclear complex [Pd2(CNXyl)6][PF6]2 (2) resulted in the formation of 3. The molecular structure of the complex 4 was determined by X-ray crystallography and spectroscopic analysis.

Original languageEnglish
Pages (from-to)2457-2464
Number of pages8
JournalJournal of Organometallic Chemistry
Volume691
Issue number11
DOIs
Publication statusPublished - May 15 2006
Externally publishedYes

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Spectroscopic analysis
X ray crystallography
X Ray Crystallography
Molecular Structure
Molecular structure
spectroscopic analysis
triangles
crystallography
molecular structure
x rays

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

Hexapalladium cluster : Unique cluster construction reaction of cyclic Pd3(CNC6H3Me2-2,6) 6 and linear [Pd3(CNC6H3Me2-2,6) 8]2+. / Ohashi, Masato; Yi, Jianjun; Shimizu, Daisuke; Yamagata, Tsuneaki; Ohshima, Takashi; Mashima, Kazushi.

In: Journal of Organometallic Chemistry, Vol. 691, No. 11, 15.05.2006, p. 2457-2464.

Research output: Contribution to journalArticle

Ohashi, Masato ; Yi, Jianjun ; Shimizu, Daisuke ; Yamagata, Tsuneaki ; Ohshima, Takashi ; Mashima, Kazushi. / Hexapalladium cluster : Unique cluster construction reaction of cyclic Pd3(CNC6H3Me2-2,6) 6 and linear [Pd3(CNC6H3Me2-2,6) 8]2+. In: Journal of Organometallic Chemistry. 2006 ; Vol. 691, No. 11. pp. 2457-2464.
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AU - Yi, Jianjun

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AU - Yamagata, Tsuneaki

AU - Ohshima, Takashi

AU - Mashima, Kazushi

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