High-concentration niobium (V) doping into TiO2 nanoparticles synthesized by thermal plasma processing

Chenning Zhang, Masashi Ikeda, Tetsuo Uchikoshi, Ji Guang Li, Takayuki Watanabe, Takamasa Ishigaki

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

High-concentration niobium (V)-doped titanium dioxide (TiO2) nanoparticles of the nonequilibrium chemical composition have been synthesized via Ar/O2 radio-frequency thermal plasma oxidation of mist precursor solutions with various Nb5+ concentrations (Nb/(Ti + Nb) = 0-25.0 at.%). The solubility as high as ∼25.0 at.% has not been achieved before by wet-chemical techniques. The preferable anatase formation was attained in the plasma-synthesized powders and was enhanced by the niobium doping. All the powders were heated at high temperatures (600-800 °C) to investigate their phase transformation, band gap variation, inter-particulate binding behavior, and photocatalytic stability. The transformation from anatase to rutile was effectively inhibited by increasing the Nb5+ content. The Nb 5+ doping prevented the band gap of TiO2 from narrowing after the heating. At high temperatures, Nb5+ doping could not only preserve particle size but also prevent inter-particulate binding. High concentration (25.0 at.%) Nb5+ doping retained the photocatalytic performance almost invariably irrespective of being thermally treated.

Original languageEnglish
Pages (from-to)658-671
Number of pages14
JournalJournal of Materials Research
Volume26
Issue number5
DOIs
Publication statusPublished - Mar 14 2011
Externally publishedYes

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All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

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