Abstract
We report the fabrication of polarization-sensitive photovoltaic devices made of hetero-junction type vacuum-sublimed multilayer films composed of aligned 3,4,9,10-perylenetetracarboxylic-bis-benzimidazole (aligned-PTCBI) and titanyl phthalocyanine (TiOPc). The PTCBI layer was successfully made to be well aligned without losing high photovoltaic power-conversion efficiency. High polarization sensitivity was achieved at around 540 nm. The device configuration was ITO/In/aligned-PTCBI/TiOPc/PEDOT:PSS/Au and the thickness of each layer was optimized for polarization-sensitive photo-detection. The power-conversion efficiencies under the polarized white light parallel and perpendicular to the molecular-orientation axis, through the ITO electrode were 0.78% and 0.45%, respectively. The ratio of short-circuit current, parallel to perpendicular, was 1.66. This device can be used as transparent photo-detectors, because the transmittance of the Au electrode was about 40% at 500-600nm. The short-circuit current ratio was increased to 3.0, when 5 10nm monochromatic polarized light through the Au electrode was used.
Original language | English |
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Article number | 593811 |
Pages (from-to) | 1-8 |
Number of pages | 8 |
Journal | Proceedings of SPIE - The International Society for Optical Engineering |
Volume | 5938 |
DOIs | |
Publication status | Published - 2005 |
Event | Organic Photovoltaics VI - San Diego, CA, United States Duration: Aug 2 2005 → Aug 4 2005 |
All Science Journal Classification (ASJC) codes
- Electronic, Optical and Magnetic Materials
- Condensed Matter Physics
- Computer Science Applications
- Applied Mathematics
- Electrical and Electronic Engineering