Abstract
A novel metal-organic framework, (Hpy)2[Zn2(ox)3]·nH2O (n = 0, 1), having a pyridinium cation, was newly synthesized, and the crystal structures were determined. The hydrated compound shows a high proton conductivity of 2.2 × 10-3 S cm-1 at 298 K and 98% relative humidity. Single crystal XRD analysis revealed a rotational displacement factor for the hydrated pyridinium ring and elongated water site that is thought to cause the high proton conductivity.
| Original language | English |
|---|---|
| Pages (from-to) | 8267-8270 |
| Number of pages | 4 |
| Journal | Inorganic Chemistry |
| Volume | 55 |
| Issue number | 17 |
| DOIs | |
| Publication status | Published - Sep 6 2016 |
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All Science Journal Classification (ASJC) codes
- Physical and Theoretical Chemistry
- Inorganic Chemistry
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High Proton Conductivity of Zinc Oxalate Coordination Polymers Mediated by a Hydrogen Bond with Pyridinium. / Yamada, Teppei; Nankawa, Takuya.
In: Inorganic Chemistry, Vol. 55, No. 17, 06.09.2016, p. 8267-8270.Research output: Contribution to journal › Article
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TY - JOUR
T1 - High Proton Conductivity of Zinc Oxalate Coordination Polymers Mediated by a Hydrogen Bond with Pyridinium
AU - Yamada, Teppei
AU - Nankawa, Takuya
PY - 2016/9/6
Y1 - 2016/9/6
N2 - A novel metal-organic framework, (Hpy)2[Zn2(ox)3]·nH2O (n = 0, 1), having a pyridinium cation, was newly synthesized, and the crystal structures were determined. The hydrated compound shows a high proton conductivity of 2.2 × 10-3 S cm-1 at 298 K and 98% relative humidity. Single crystal XRD analysis revealed a rotational displacement factor for the hydrated pyridinium ring and elongated water site that is thought to cause the high proton conductivity.
AB - A novel metal-organic framework, (Hpy)2[Zn2(ox)3]·nH2O (n = 0, 1), having a pyridinium cation, was newly synthesized, and the crystal structures were determined. The hydrated compound shows a high proton conductivity of 2.2 × 10-3 S cm-1 at 298 K and 98% relative humidity. Single crystal XRD analysis revealed a rotational displacement factor for the hydrated pyridinium ring and elongated water site that is thought to cause the high proton conductivity.
UR - http://www.scopus.com/inward/record.url?scp=84986222542&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84986222542&partnerID=8YFLogxK
U2 - 10.1021/acs.inorgchem.6b01534
DO - 10.1021/acs.inorgchem.6b01534
M3 - Article
AN - SCOPUS:84986222542
VL - 55
SP - 8267
EP - 8270
JO - Inorganic Chemistry
JF - Inorganic Chemistry
SN - 0020-1669
IS - 17
ER -