High-spin state instability in nitroxide triradical coupled through m-phenylene

Kazunari Yoshizawa, Takako Kuga, Masashi Hatanaka, Kazuyoshi Tanaka, Tokio Yamabe

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

The electronic structure of 2-methoxy-1,3,5-benzenetriyltris (N-hydronitroxide) (MBTN) is discussed with the ab initio molecular orbital method at the second-order Møller-Plesset perturbation level of theory. The result explains why high-spin states are unstable in some hindered nitroxide di-and triradicals coupled through m-phenylene.

Original languageEnglish
Pages (from-to)1765-1766
Number of pages2
JournalSynthetic Metals
Volume85
Issue number1-3
DOIs
Publication statusPublished - Mar 15 1997
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

Fingerprint Dive into the research topics of 'High-spin state instability in nitroxide triradical coupled through m-phenylene'. Together they form a unique fingerprint.

Cite this