Highly efficient chemoselective hydrogenolysis of epoxides catalyzed by a (η5-C5(CH3)5)Ru complex bearing a 2-(diphenylphosphino)ethylamine ligand

Masato Ito; Makoto Hirakawa; Akihide Osaku; Takao Ikariya

doi:10.1021/om034006j

Highly efficient chemoselective hydrogenolysis of epoxides catalyzed by a (η⁵-C₅(CH₃)₅)Ru complex bearing a 2-(diphenylphosphino)ethylamine ligand

Masato Ito, Makoto Hirakawa, Akihide Osaku, Takao Ikariya

Research output: Contribution to journal › Article › peer-review

85 Citations (Scopus)

Abstract

Terminal epoxides are hydrogenolyzed to give secondary alcohols with high regioselectivity using the ternary catalyst system of Cp*RuCl(cod)-2-(diphenyl-phosphino)ethylamine (1a)-KOH (Cp* = η⁵-C₅(CH₃)₅, cod = 1,5-cyclooctadiene) in 2-propanol under mild conditions.

Original language	English
Pages (from-to)	4190-4192
Number of pages	3
Journal	Organometallics
Volume	22
Issue number	21
DOIs	https://doi.org/10.1021/om034006j
Publication status	Published - Oct 13 2003
Externally published	Yes

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om034006j

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abstract = "Terminal epoxides are hydrogenolyzed to give secondary alcohols with high regioselectivity using the ternary catalyst system of Cp*RuCl(cod)-2-(diphenyl-phosphino)ethylamine (1a)-KOH (Cp* = η5-C5(CH3)5, cod = 1,5-cyclooctadiene) in 2-propanol under mild conditions.",

author = "Masato Ito and Makoto Hirakawa and Akihide Osaku and Takao Ikariya",

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AU - Ito, Masato

AU - Hirakawa, Makoto

AU - Osaku, Akihide

AU - Ikariya, Takao

PY - 2003/10/13

Y1 - 2003/10/13

N2 - Terminal epoxides are hydrogenolyzed to give secondary alcohols with high regioselectivity using the ternary catalyst system of Cp*RuCl(cod)-2-(diphenyl-phosphino)ethylamine (1a)-KOH (Cp* = η5-C5(CH3)5, cod = 1,5-cyclooctadiene) in 2-propanol under mild conditions.

AB - Terminal epoxides are hydrogenolyzed to give secondary alcohols with high regioselectivity using the ternary catalyst system of Cp*RuCl(cod)-2-(diphenyl-phosphino)ethylamine (1a)-KOH (Cp* = η5-C5(CH3)5, cod = 1,5-cyclooctadiene) in 2-propanol under mild conditions.

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Highly efficient chemoselective hydrogenolysis of epoxides catalyzed by a (η⁵-C₅(CH₃)₅)Ru complex bearing a 2-(diphenylphosphino)ethylamine ligand

Abstract

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