Highly efficient synthesis of aldenamines from carboxamides by iridium-catalyzed silane-reduction/dehydration under mild conditions

Yukihiro Motoyama, Masaharu Aoki, Naoki Takaoka, Ryuta Aoto, Hideo Nagashima

Research output: Contribution to journalArticle

93 Citations (Scopus)

Abstract

The combination of IrCl(CO)(PPh3)2 with 1,1,3,3-tetramethyldisiloxane or poly(methylhydrosiloxane) (PMHS) is found to be an efficient catalyst system for the preparation of aldenamines from carboxamides; in particular, facile removal of silicone and iridium residues from the product can be achieved by the use of PMHS.

Original languageEnglish
Pages (from-to)1574-1576
Number of pages3
JournalChemical Communications
Issue number12
DOIs
Publication statusPublished - 2009

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Fingerprint Dive into the research topics of 'Highly efficient synthesis of aldenamines from carboxamides by iridium-catalyzed silane-reduction/dehydration under mild conditions'. Together they form a unique fingerprint.

  • Cite this