Highly enantioselective Baeyer-Villiger oxidation using Zr(salen) complex as catalyst

Akira Watanabe; Tatsuya Uchida; Katsuji Ito; Tsutomu Katsuki

doi:10.1016/S0040-4039(02)00831-6

Highly enantioselective Baeyer-Villiger oxidation using Zr(salen) complex as catalyst

Akira Watanabe, Tatsuya Uchida, Katsuji Ito, Tsutomu Katsuki

Division for Experimental Natural Science

Research output: Contribution to journal › Article › peer-review

104 Citations (Scopus)

Abstract

(R, R)-Zr(salen) complex was found to serve as an efficient catalyst for asymmetric Baeyer-Villiger oxidation of pro-chiral and racemic ketones using urea·hydrogen peroxide as the terminal oxidant: for example, high enantioselectivity of 87% ee was achieved in the Baeyer-Villiger reaction of 3-phenylcyclobutanone.

Original language	English
Pages (from-to)	4481-4485
Number of pages	5
Journal	Tetrahedron Letters
Volume	43
Issue number	25
DOIs	https://doi.org/10.1016/S0040-4039(02)00831-6
Publication status	Published - Jan 1 2002

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

Access to Document

10.1016/S0040-4039(02)00831-6

Cite this

@article{ea7b3be3898b4df1ba90c77a86004e03,

title = "Highly enantioselective Baeyer-Villiger oxidation using Zr(salen) complex as catalyst",

abstract = "(R, R)-Zr(salen) complex was found to serve as an efficient catalyst for asymmetric Baeyer-Villiger oxidation of pro-chiral and racemic ketones using urea·hydrogen peroxide as the terminal oxidant: for example, high enantioselectivity of 87% ee was achieved in the Baeyer-Villiger reaction of 3-phenylcyclobutanone.",

author = "Akira Watanabe and Tatsuya Uchida and Katsuji Ito and Tsutomu Katsuki",

year = "2002",

month = jan,

day = "1",

doi = "10.1016/S0040-4039(02)00831-6",

language = "English",

volume = "43",

pages = "4481--4485",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Limited",

number = "25",

}

TY - JOUR

T1 - Highly enantioselective Baeyer-Villiger oxidation using Zr(salen) complex as catalyst

AU - Watanabe, Akira

AU - Uchida, Tatsuya

AU - Ito, Katsuji

AU - Katsuki, Tsutomu

PY - 2002/1/1

Y1 - 2002/1/1

N2 - (R, R)-Zr(salen) complex was found to serve as an efficient catalyst for asymmetric Baeyer-Villiger oxidation of pro-chiral and racemic ketones using urea·hydrogen peroxide as the terminal oxidant: for example, high enantioselectivity of 87% ee was achieved in the Baeyer-Villiger reaction of 3-phenylcyclobutanone.

AB - (R, R)-Zr(salen) complex was found to serve as an efficient catalyst for asymmetric Baeyer-Villiger oxidation of pro-chiral and racemic ketones using urea·hydrogen peroxide as the terminal oxidant: for example, high enantioselectivity of 87% ee was achieved in the Baeyer-Villiger reaction of 3-phenylcyclobutanone.

UR - http://www.scopus.com/inward/record.url?scp=0037124439&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0037124439&partnerID=8YFLogxK

U2 - 10.1016/S0040-4039(02)00831-6

DO - 10.1016/S0040-4039(02)00831-6

M3 - Article

AN - SCOPUS:0037124439

VL - 43

SP - 4481

EP - 4485

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 25

ER -

Highly enantioselective Baeyer-Villiger oxidation using Zr(salen) complex as catalyst

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this