Highly enantioselective hydrophosphonylation of aldehydes

Base-enhanced aluminum-salalen catalysis

Keitaro Suyama, Yoshifumi Sakai, Kazuhiro Matsumoto, Bunnai Saito, Tsutomu Katsuki

Research output: Contribution to journalArticle

88 Citations (Scopus)

Abstract

(Chemical Equation Presented) The dimethyl phosphonate hydrophosphonylation of conjugated- and non-conjugated aldehydes into their correspond ing α-hydroxy phosphonates was achieved using chiral aluminum-salalen complex 1 (see scheme).

Original languageEnglish
Pages (from-to)797-799
Number of pages3
JournalAngewandte Chemie - International Edition
Volume49
Issue number4
DOIs
Publication statusPublished - Jan 18 2010

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Organophosphonates
Aldehydes
Aluminum
Catalysis
dimethyl hydrogen phosphite

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

Highly enantioselective hydrophosphonylation of aldehydes : Base-enhanced aluminum-salalen catalysis. / Suyama, Keitaro; Sakai, Yoshifumi; Matsumoto, Kazuhiro; Saito, Bunnai; Katsuki, Tsutomu.

In: Angewandte Chemie - International Edition, Vol. 49, No. 4, 18.01.2010, p. 797-799.

Research output: Contribution to journalArticle

Suyama, Keitaro ; Sakai, Yoshifumi ; Matsumoto, Kazuhiro ; Saito, Bunnai ; Katsuki, Tsutomu. / Highly enantioselective hydrophosphonylation of aldehydes : Base-enhanced aluminum-salalen catalysis. In: Angewandte Chemie - International Edition. 2010 ; Vol. 49, No. 4. pp. 797-799.
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