Highly enantioselective hydrophosphonylation of aldehydes: Base-enhanced aluminum-salalen catalysis

Keitaro Suyama, Yoshifumi Sakai, Kazuhiro Matsumoto, Bunnai Saito, Tsutomu Katsuki

Research output: Contribution to journalArticle

91 Citations (Scopus)

Abstract

(Chemical Equation Presented) The dimethyl phosphonate hydrophosphonylation of conjugated- and non-conjugated aldehydes into their correspond ing α-hydroxy phosphonates was achieved using chiral aluminum-salalen complex 1 (see scheme).

Original languageEnglish
Pages (from-to)797-799
Number of pages3
JournalAngewandte Chemie - International Edition
Volume49
Issue number4
DOIs
Publication statusPublished - Jan 18 2010

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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