Highly enantioselective recognition of dicarboxylic acid substrates by the control of nonlinear responses

Tomohiro Ikeda, Osamu Hirata, Masayuki Takeuchi, Seiji Shinkai

Research output: Contribution to journalArticle

53 Citations (Scopus)

Abstract

An allosteric host, in which the molecular information of the chiral guest was precisely introduced, exhibits unconventional enantioselectivity toward the target enantiomer even under the conditions of a -20% enantiomeric excess (ee) mixture within a certain concentration window. This is effected by incorporation of the structural information of the enantiomer into the host and the utilization of multiple equilibrium.

Original languageEnglish
Pages (from-to)16008-16009
Number of pages2
JournalJournal of the American Chemical Society
Volume128
Issue number50
DOIs
Publication statusPublished - Dec 20 2006

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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