Highly selective synthesis of biphenyl by the Pd(OAc)2/HPA/O2/AcOH catalyst system

Makoto Okamoto, Midori Watanabe, Teizo Yamaji

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

A new catalytic system, dimerization of benzene with 100% selectivity and 19% yield under the conditions of 130 C, 10 atm and 4 h. PdHPMo12O 40 itself was also found to act as a catalyst to give 95% of selectivity of biphenyl with a lower yield. A plausible mechanism of this system is also discussed.

Original languageEnglish
Pages (from-to)59-65
Number of pages7
JournalJournal of Organometallic Chemistry
Volume664
Issue number1-2
DOIs
Publication statusPublished - Dec 16 2002

Fingerprint

Dimerization
Catalyst selectivity
Benzene
selectivity
catalysts
Catalysts
synthesis
dimerization
benzene
palladium(II) acetate
diphenyl

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

Highly selective synthesis of biphenyl by the Pd(OAc)2/HPA/O2/AcOH catalyst system. / Okamoto, Makoto; Watanabe, Midori; Yamaji, Teizo.

In: Journal of Organometallic Chemistry, Vol. 664, No. 1-2, 16.12.2002, p. 59-65.

Research output: Contribution to journalArticle

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