Homo- and heterobismetal complexes of 5-hydroxy-10.15.25.30-tetrakis- (pentafIuorophenyl)-substituted [26]hexaphyrin(1.1.1.1.1.1)

Taro Koide, Gengo Kashiwazaki, Ko Furukawa, Atsuhiro Osuka

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

Metalation of meso-free 5,10,20,25-tetrakis(pentafluorophenyl)-substituted [26]hexaphyrin(1.1.1.1.1.1) (4) with CuII and ZnII ions afforded homodinuclear complexes 6 and 7, respectively. A demetalation- remetalation protocol provided monozinc(II) complex 9 selectively, from which copper(II) - zinc(II) heterodi-nuclear complex 10 was prepared effectively.

Original languageEnglish
Pages (from-to)4595-4597
Number of pages3
JournalInorganic chemistry
Volume48
Issue number11
DOIs
Publication statusPublished - Jun 1 2009

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Zinc
Copper
zinc
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All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Cite this

Homo- and heterobismetal complexes of 5-hydroxy-10.15.25.30-tetrakis- (pentafIuorophenyl)-substituted [26]hexaphyrin(1.1.1.1.1.1). / Koide, Taro; Kashiwazaki, Gengo; Furukawa, Ko; Osuka, Atsuhiro.

In: Inorganic chemistry, Vol. 48, No. 11, 01.06.2009, p. 4595-4597.

Research output: Contribution to journalArticle

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