Metalation of meso-free 5,10,20,25-tetrakis(pentafluorophenyl)-substituted hexaphyrin(188.8.131.52.1.1) (4) with CuII and ZnII ions afforded homodinuclear complexes 6 and 7, respectively. A demetalation- remetalation protocol provided monozinc(II) complex 9 selectively, from which copper(II) - zinc(II) heterodi-nuclear complex 10 was prepared effectively.
All Science Journal Classification (ASJC) codes
- Physical and Theoretical Chemistry
- Inorganic Chemistry