Homogeneous catalysis of platinum(II) complexes in photochemical hydrogen production from water

Research output: Contribution to journalReview article

179 Citations (Scopus)

Abstract

This review concentrates on the Pt(II)-catalyzed reduction of water into molecular hydrogen, with emphasis given to the works undertaken thus far by the authors' group. The homogeneous catalysis of (i) dinuclear platinum(II) complexes, (ii) mononuclear platinum(II) complexes, (iii) platinum(II) complexes having electron-acceptor groups, and (iv) platinum(II) complexes having photosensitizing groups is described. The dependences of the H2-evolving activity on the metal-metal interaction, the Pt(II) dz2 orbital energy, the steric factor, and the electron-acceptor ability are discussed. Moreover, the first active model of a photo-hydrogen-evolving molecular device made up of a tris(2,2′-bipyridine)ruthenium(II) derivative and a homogeneous platinum(II) catalyst is discussed.

Original languageEnglish
Pages (from-to)2753-2766
Number of pages14
JournalCoordination Chemistry Reviews
Volume251
Issue number21-24
DOIs
Publication statusPublished - Nov 1 2007

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hydrogen production
Hydrogen production
Platinum
Catalysis
catalysis
platinum
Water
water
Hydrogen
Metals
Ruthenium
Electrons
hydrogen
metals
ruthenium
electrons
Derivatives
catalysts
orbitals
Catalysts

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

Homogeneous catalysis of platinum(II) complexes in photochemical hydrogen production from water. / Sakai, Ken; Ozawa, Hironobu.

In: Coordination Chemistry Reviews, Vol. 251, No. 21-24, 01.11.2007, p. 2753-2766.

Research output: Contribution to journalReview article

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