Honeycomb-like perovskite oxide electrocatalyst for a hybrid Li-air battery

Young Wan Ju, Seonyoung Yoo, Limin Guo, Changmin Kim, Atsushi Inoishi, Hu Young Jeong, Jeeyoung Shin, Tatsumi Ishihara, Sung Dae Yim, Guntae Kim

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Honeycomb-like Nd0.7Sr0.3CoO3-δ has been successfully prepared with a PMMA hard-template for an energy storage system and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and nitrogen adsorption-desorption measurements. The prepared 3-dimensionally (3-D) ordered mesoporous Nd0.7Sr0.3CoO3-δ(3DOM-NSC) has a well-developed mesoporous structure and has high specific surface area (22.0 m2 g-1). The catalytic activity for the oxygen reduction reaction (ORR) in 0.1 M KOH solution has been studied by using a rotating-ring-disk electrode (RRDE). In the ORR test, a limiting current density of 5.83 mA cm-2 at 0.7 V (vs. Hg/HgO) with 1600 rpm was obtained, a value comparable with that of Pt/C. Moreover, the ORR mainly favors a direct four-electron pathway. Consequently, the high electrocatalytic activity and mesoporous structure result in stable, excellent performance in a hybrid Li-air cell.

Original languageEnglish
Pages (from-to)A2651-A2655
JournalJournal of the Electrochemical Society
Volume162
Issue number14
DOIs
Publication statusPublished - Jan 1 2015

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Electrocatalysts
Perovskite
Oxides
Oxygen
Air
Polymethyl Methacrylate
Specific surface area
Energy storage
Catalyst activity
Desorption
Current density
Nitrogen
Transmission electron microscopy
Adsorption
X ray diffraction
Scanning electron microscopy
Electrodes
Electrons
perovskite

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Renewable Energy, Sustainability and the Environment
  • Surfaces, Coatings and Films
  • Electrochemistry
  • Materials Chemistry

Cite this

Honeycomb-like perovskite oxide electrocatalyst for a hybrid Li-air battery. / Ju, Young Wan; Yoo, Seonyoung; Guo, Limin; Kim, Changmin; Inoishi, Atsushi; Jeong, Hu Young; Shin, Jeeyoung; Ishihara, Tatsumi; Yim, Sung Dae; Kim, Guntae.

In: Journal of the Electrochemical Society, Vol. 162, No. 14, 01.01.2015, p. A2651-A2655.

Research output: Contribution to journalArticle

Ju, YW, Yoo, S, Guo, L, Kim, C, Inoishi, A, Jeong, HY, Shin, J, Ishihara, T, Yim, SD & Kim, G 2015, 'Honeycomb-like perovskite oxide electrocatalyst for a hybrid Li-air battery', Journal of the Electrochemical Society, vol. 162, no. 14, pp. A2651-A2655. https://doi.org/10.1149/2.0311514jes
Ju, Young Wan ; Yoo, Seonyoung ; Guo, Limin ; Kim, Changmin ; Inoishi, Atsushi ; Jeong, Hu Young ; Shin, Jeeyoung ; Ishihara, Tatsumi ; Yim, Sung Dae ; Kim, Guntae. / Honeycomb-like perovskite oxide electrocatalyst for a hybrid Li-air battery. In: Journal of the Electrochemical Society. 2015 ; Vol. 162, No. 14. pp. A2651-A2655.
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