Hybrid Bi2SiO5 mesoporous microspheres with light response for environment decontamination

Ling Zhang, Wenzhong Wang, Songmei Sun, Jiehui Xu, Meng Shang, Jia Ren

Research output: Contribution to journalArticle

36 Citations (Scopus)

Abstract

A hybrid mesostructured photocatalyst prepared by using the " postsynthetic modification" approach with the periodic mesoporous organosilicas (PMO) framework and bismuth nitrate was studied. The morphology and structure of the hybrid Bi2SiO5 photocatalyst were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM) and N2 adsorption-desorption isotherms. These results of characterization show that the as-prepared Bi2SiO5 keeps a semi-ordered mesostructure as the PMO framework. The results of density functional theory calculations indicated that the conduction band bottom of Bi2SiO5 mainly consist of Bi 6s orbits and O 2p, O 2s, while the valence band top mainly consist of Si 3p, O 2p, and Bi 5d orbits. The as-prepared Bi2SiO5 exhibited efficient photocatalytic activity in the decomposition of a widely used dye, tetraethylated rhodamine (RhB), and phenol in water under the simulative sunlight irradiation. Further, the photocatalytic experiment results show that the hybrid Bi2SiO5 synthesized based on PMO was more efficient than the pure mesoporous Bi2SiO5 in decomposing the organic pollutant, which means the hybrid organic groups dispersed in the PMO framework is advantageous to improve the efficiency of the photocatalyst.

Original languageEnglish
Pages (from-to)97-101
Number of pages5
JournalApplied Catalysis B: Environmental
Volume100
Issue number1-2
DOIs
Publication statusPublished - Aug 23 2010

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Decontamination
Photocatalysts
Microspheres
Orbits
Rhodamines
Organic pollutants
Valence bands
Phenol
Conduction bands
Bismuth
Phenols
Density functional theory
Isotherms
bismuth
Nitrates
Desorption
Coloring Agents
Dyes
Irradiation
organic pollutant

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Environmental Science(all)
  • Process Chemistry and Technology

Cite this

Hybrid Bi2SiO5 mesoporous microspheres with light response for environment decontamination. / Zhang, Ling; Wang, Wenzhong; Sun, Songmei; Xu, Jiehui; Shang, Meng; Ren, Jia.

In: Applied Catalysis B: Environmental, Vol. 100, No. 1-2, 23.08.2010, p. 97-101.

Research output: Contribution to journalArticle

Zhang, Ling ; Wang, Wenzhong ; Sun, Songmei ; Xu, Jiehui ; Shang, Meng ; Ren, Jia. / Hybrid Bi2SiO5 mesoporous microspheres with light response for environment decontamination. In: Applied Catalysis B: Environmental. 2010 ; Vol. 100, No. 1-2. pp. 97-101.
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