Hydrogen generation from pure water using Al-Sn powders consolidated through high-pressure torsion

Fan Zhang, Ryo Yonemoto, Makoto Arita, Zenji Horita

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

Al-Sn binary alloys are fabricated by powder consolidation using high-pressure torsion (HPT). The HPT-processed samples are immersed in pure water and hydrogen generation behavior is investigated with respect to the imposed strain through the HPT processing at a selected temperature in the range of 297-333 K. Microstructures of HPT-processed alloys are analyzed by X-ray diffraction, transmission electron microscopy (TEM), electron probe microanalysis (EPMA) and electron back scattered diffraction (EBSD) analysis. Results show that it is important to add more than 60 wt% of Sn to activate hydrogen generation from the Al-Sn alloys in pure water. TEM and EBSD images reveal significant grain refinement while EPMA results exhibit homogenous distribution of elements achieved by HPT. The grain refinement and distribution of elements attained by HPT processing influence greatly the hydrogen generation rate and yield of the alloys. An Al-80 wt% Sn alloy with an average grain size of ∼270 nm exhibits the highest hydrogen yield and generation rate in pure water at 333 K.

Original languageEnglish
Pages (from-to)775-782
Number of pages8
JournalJournal of Materials Research
Volume31
Issue number6
DOIs
Publication statusPublished - Mar 28 2016

Fingerprint

Torsional stress
Powders
torsion
Hydrogen
Water
hydrogen
water
Grain refinement
Electron probe microanalysis
electron probes
microanalysis
Diffraction
diffraction
Transmission electron microscopy
transmission electron microscopy
Electrons
consolidation
Binary alloys
binary alloys
Processing

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

Cite this

Hydrogen generation from pure water using Al-Sn powders consolidated through high-pressure torsion. / Zhang, Fan; Yonemoto, Ryo; Arita, Makoto; Horita, Zenji.

In: Journal of Materials Research, Vol. 31, No. 6, 28.03.2016, p. 775-782.

Research output: Contribution to journalArticle

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