Hydrogen isotope separation using particle beds of LaNi3Al2 hydride

S. Fukada, K. Fuchinoue, M. Nishikawa

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

An experimental study was carried out for evaluating the performance of hydrogen isotope separation using an LaNi3Al2 hydride bed. The isotope effect in the uptake of hydrogen isotopes and the rate constants of hydriding and isotopic exchange between hydrogen and deuterium are given as indications of its effectiveness. These values were determined on the basis of the comparison of experimental data with numerical solutions to the material balance equation for hydrogen or deuterium in a bed. The uptake of deuterium is larger than that of hydrogen below 200 °C. The activation energy of the rate constant of isotopic exchange is 31.8 kJ mol-1, while that of the hydriding rate constant increases with increasing hydrogen concentration in the influent stream. The height equivalent to a theoretical plate in the LaNi3Al2 bed above 200 °C is comparable with that in a Pd bed.

Original languageEnglish
Pages (from-to)49-55
Number of pages7
JournalJournal of Alloys and Compounds
Volume201
Issue number1-2
DOIs
Publication statusPublished - Nov 12 1993

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Hydrides
Isotopes
Hydrogen
Deuterium
Rate constants
Activation energy

All Science Journal Classification (ASJC) codes

  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

Cite this

Hydrogen isotope separation using particle beds of LaNi3Al2 hydride. / Fukada, S.; Fuchinoue, K.; Nishikawa, M.

In: Journal of Alloys and Compounds, Vol. 201, No. 1-2, 12.11.1993, p. 49-55.

Research output: Contribution to journalArticle

Fukada, S. ; Fuchinoue, K. ; Nishikawa, M. / Hydrogen isotope separation using particle beds of LaNi3Al2 hydride. In: Journal of Alloys and Compounds. 1993 ; Vol. 201, No. 1-2. pp. 49-55.
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