Hydrogen production from water catalyzed by an air-stable di-iron complex with a bio-relevant Fe 2(μ-S) 2 core

Toshiki Yamaguchi; Shigeyuki Masaoka; Ken Sakai

doi:10.1246/cl.2009.434

Hydrogen production from water catalyzed by an air-stable di-iron complex with a bio-relevant Fe ₂(μ-S) ₂ core

Toshiki Yamaguchi, Shigeyuki Masaoka, Ken Sakai

Inorganic and Analytical Chemistry

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

An air-stable dinuclear iron-dithiolene complex with an Fe ₂(μ-S) ₂ core, [Fe ^III(mnt) ₂] ₂ ^2- (mnt = maleonitriledithiolate), has been found to serve as an electrode catalyst toward the reduction of water into molecular hydrogen with an overpotential of 560 mV. The acid form of a buffer reagent, such as CH ₃CO ₂H, has been found to serve as a major proton mediator during the electrocatalytie hydrogen evolution.

Original language	English
Pages (from-to)	434-435
Number of pages	2
Journal	Chemistry Letters
Volume	38
Issue number	5
DOIs	https://doi.org/10.1246/cl.2009.434
Publication status	Published - Jul 20 2009

All Science Journal Classification (ASJC) codes

Chemistry(all)

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10.1246/cl.2009.434

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