Hydrogenation effects in metalloporphycenes: Synthesis and redox behavior of Ni(II)-tetra(n-propyl)dihydroporphycene

Toru Okawara; Koichi Hashimoto; Masaaki Abe; Hisashi Shimakoshi; Yoshio Hisaeda

doi:10.1039/c2cc30991b

Hydrogenation effects in metalloporphycenes: Synthesis and redox behavior of Ni(II)-tetra(n-propyl)dihydroporphycene

Toru Okawara, Koichi Hashimoto, Masaaki Abe, Hisashi Shimakoshi, Yoshio Hisaeda

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

Hydrogenated tetrapropylporphycenes, 2,3-dihydro-2,7,12,17-tetrapropylporphycene 1 and its Ni^II complex 2, have been prepared and the hydrogenation effects on their electronic structure characterized. A one-electron reduction of 2 promotes dehalogenation of organic halides whose observation is unprecedented for the porphycene compounds.

Original language	English
Pages (from-to)	5413-5415
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	44
DOIs	https://doi.org/10.1039/c2cc30991b
Publication status	Published - May 7 2012

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "Hydrogenated tetrapropylporphycenes, 2,3-dihydro-2,7,12,17-tetrapropylporphycene 1 and its NiII complex 2, have been prepared and the hydrogenation effects on their electronic structure characterized. A one-electron reduction of 2 promotes dehalogenation of organic halides whose observation is unprecedented for the porphycene compounds.",

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AU - Okawara, Toru

AU - Hashimoto, Koichi

AU - Abe, Masaaki

AU - Shimakoshi, Hisashi

AU - Hisaeda, Yoshio

PY - 2012/5/7

Y1 - 2012/5/7

N2 - Hydrogenated tetrapropylporphycenes, 2,3-dihydro-2,7,12,17-tetrapropylporphycene 1 and its NiII complex 2, have been prepared and the hydrogenation effects on their electronic structure characterized. A one-electron reduction of 2 promotes dehalogenation of organic halides whose observation is unprecedented for the porphycene compounds.

AB - Hydrogenated tetrapropylporphycenes, 2,3-dihydro-2,7,12,17-tetrapropylporphycene 1 and its NiII complex 2, have been prepared and the hydrogenation effects on their electronic structure characterized. A one-electron reduction of 2 promotes dehalogenation of organic halides whose observation is unprecedented for the porphycene compounds.

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Hydrogenation effects in metalloporphycenes: Synthesis and redox behavior of Ni(II)-tetra(n-propyl)dihydroporphycene

Abstract

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