Hydrogenation effects in metalloporphycenes: Synthesis and redox behavior of Ni(ii)-tetra(n-propyl)dihydroporphycene

Toru Okawara, Koichi Hashimoto, Masaaki Abe, Hisashi Shimakoshi, Yoshio Hisaeda

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

Hydrogenated tetrapropylporphycenes, 2,3-dihydro-2,7,12,17- tetrapropylporphycene 1 and its Ni II complex 2, have been prepared and the hydrogenation effects on their electronic structure characterized. A one-electron reduction of 2 promotes dehalogenation of organic halides whose observation is unprecedented for the porphycene compounds.

Original languageEnglish
Pages (from-to)5413-5415
Number of pages3
JournalChemical Communications
Volume48
Issue number44
DOIs
Publication statusPublished - Jun 4 2012

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Dehalogenation
Hydrogenation
Electronic structure
Electrons
Oxidation-Reduction
porphycene

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Hydrogenation effects in metalloporphycenes : Synthesis and redox behavior of Ni(ii)-tetra(n-propyl)dihydroporphycene. / Okawara, Toru; Hashimoto, Koichi; Abe, Masaaki; Shimakoshi, Hisashi; Hisaeda, Yoshio.

In: Chemical Communications, Vol. 48, No. 44, 04.06.2012, p. 5413-5415.

Research output: Contribution to journalArticle

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