Hydrogenation effects in metalloporphycenes: Synthesis and redox behavior of Ni(II)-tetra(n-propyl)dihydroporphycene

Toru Okawara, Koichi Hashimoto, Masaaki Abe, Hisashi Shimakoshi, Yoshio Hisaeda

Research output: Contribution to journalArticlepeer-review

6 Citations (Scopus)

Abstract

Hydrogenated tetrapropylporphycenes, 2,3-dihydro-2,7,12,17-tetrapropylporphycene 1 and its NiII complex 2, have been prepared and the hydrogenation effects on their electronic structure characterized. A one-electron reduction of 2 promotes dehalogenation of organic halides whose observation is unprecedented for the porphycene compounds.

Original languageEnglish
Pages (from-to)5413-5415
Number of pages3
JournalChemical Communications
Volume48
Issue number44
DOIs
Publication statusPublished - May 7 2012

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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