Hydrogenation of Carbon Monoxide over Mixed Catalysts Composed of Co-Ni/MnO-ZrO2 and Zeolite

Tatsumi Ishihara, Hideharu Iwakuni, Koichi Eguchi, Hiromichi Arai

    Research output: Contribution to journalArticlepeer-review

    Abstract

    The mechanical mixtures of Co-Ni/MnO-ZrO2 and zeolite were used as catalysts for the selective synthesis of gasoline by CO hydrogenation. Formation of branched-paraffins was promoted but that of higher hydrocarbons than carbon number of 10 was suppressed by combination with zeolite. The product distribution strongly depended on the type of zeolite catalyst. Pentasil zeolite was active for the formation of branched-paraffins, probably because of the cracking reaction occurring on the strong acid sites. The formation of branched-paraffins was further promoted by ion-exhange with Pt. The mixture of Co-Ni/MnO-ZrO2 and PtH-pentasil zeolite was very active for the formation of gasoline with high octane number.

    Original languageEnglish
    Pages (from-to)711-718
    Number of pages8
    JournalNIPPON KAGAKU KAISHI
    Volume1990
    Issue number7
    DOIs
    Publication statusPublished - 1990

    All Science Journal Classification (ASJC) codes

    • Chemistry(all)
    • Chemical Engineering(all)

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