Hydrogenation of N-acylcarbamates and N-acylsulfonamides catalyzed by a bifunctional [Cp*Ru(PN)] complex

Masato Ito, Lee Wei Koo, Akio Himizu, Chika Kobayashi, Ayaka Sakaguchi, Takao Ikariya

Research output: Contribution to journalArticlepeer-review

68 Citations (Scopus)

Abstract

Awakening of the Cp one: the bifunctional complex 1 facilitates the interaction with substrates bearing less electrophilic carbon atoms than ketones, epoxides, and imides. The title reaction was applicable to the reduction of Evans' asymmetric alkylation products to the chiral alcohols along with gtood recovery of the chiral oxazolidinone auxiliary. EWG=electron- withdrawing group.

Original languageEnglish
Pages (from-to)1324-1327
Number of pages4
JournalAngewandte Chemie - International Edition
Volume48
Issue number7
DOIs
Publication statusPublished - Feb 2 2009
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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