TY - JOUR
T1 - Hydrogenation of N-acylcarbamates and N-acylsulfonamides catalyzed by a bifunctional [Cp*Ru(PN)] complex
AU - Ito, Masato
AU - Koo, Lee Wei
AU - Himizu, Akio
AU - Kobayashi, Chika
AU - Sakaguchi, Ayaka
AU - Ikariya, Takao
PY - 2009/2/2
Y1 - 2009/2/2
N2 - Awakening of the Cp one: the bifunctional complex 1 facilitates the interaction with substrates bearing less electrophilic carbon atoms than ketones, epoxides, and imides. The title reaction was applicable to the reduction of Evans' asymmetric alkylation products to the chiral alcohols along with gtood recovery of the chiral oxazolidinone auxiliary. EWG=electron- withdrawing group.
AB - Awakening of the Cp one: the bifunctional complex 1 facilitates the interaction with substrates bearing less electrophilic carbon atoms than ketones, epoxides, and imides. The title reaction was applicable to the reduction of Evans' asymmetric alkylation products to the chiral alcohols along with gtood recovery of the chiral oxazolidinone auxiliary. EWG=electron- withdrawing group.
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U2 - 10.1002/anie.200805307
DO - 10.1002/anie.200805307
M3 - Article
C2 - 19130533
AN - SCOPUS:60149095135
SN - 1433-7851
VL - 48
SP - 1324
EP - 1327
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 7
ER -