Hydrolysis of Alkenyl Esters and Ethers Catalyzed by Metal Complexes

Hiroshi Aoyama, Makoto Tokunaga, Shin Ichiro Hiraiwa, Yuki Shirogane, Yasushi Obora, Yasushi Tsuji

Research output: Contribution to journalArticle

42 Citations (Scopus)

Abstract

(Equation presented) Various kinds of transition metals catalyzed the hydrolysis of alkenyl esters and ethers under buffer-free, high concentration conditions compared to usual biocatalysts. Hydrolytic kinetic resolution of cis-2-tert-butylcyclohexyl vinyl ether was achieved by chiral (salen)Co complexes with good selectivity (krel = 10.0).

Original languageEnglish
Pages (from-to)509-512
Number of pages4
JournalOrganic Letters
Volume6
Issue number4
DOIs
Publication statusPublished - Feb 19 2004
Externally publishedYes

Fingerprint

Ethers
Coordination Complexes
Transition metals
hydrolysis
esters
Hydrolysis
ethers
Buffers
Esters
Metals
Kinetics
Enzymes
metals
buffers
selectivity
transition metals
kinetics
disalicylaldehyde ethylenediamine
vinyl ether

All Science Journal Classification (ASJC) codes

  • Molecular Medicine

Cite this

Aoyama, H., Tokunaga, M., Hiraiwa, S. I., Shirogane, Y., Obora, Y., & Tsuji, Y. (2004). Hydrolysis of Alkenyl Esters and Ethers Catalyzed by Metal Complexes. Organic Letters, 6(4), 509-512. https://doi.org/10.1021/ol036228j

Hydrolysis of Alkenyl Esters and Ethers Catalyzed by Metal Complexes. / Aoyama, Hiroshi; Tokunaga, Makoto; Hiraiwa, Shin Ichiro; Shirogane, Yuki; Obora, Yasushi; Tsuji, Yasushi.

In: Organic Letters, Vol. 6, No. 4, 19.02.2004, p. 509-512.

Research output: Contribution to journalArticle

Aoyama, H, Tokunaga, M, Hiraiwa, SI, Shirogane, Y, Obora, Y & Tsuji, Y 2004, 'Hydrolysis of Alkenyl Esters and Ethers Catalyzed by Metal Complexes', Organic Letters, vol. 6, no. 4, pp. 509-512. https://doi.org/10.1021/ol036228j
Aoyama, Hiroshi ; Tokunaga, Makoto ; Hiraiwa, Shin Ichiro ; Shirogane, Yuki ; Obora, Yasushi ; Tsuji, Yasushi. / Hydrolysis of Alkenyl Esters and Ethers Catalyzed by Metal Complexes. In: Organic Letters. 2004 ; Vol. 6, No. 4. pp. 509-512.
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