Hydrolytic activity of A FeIIIZnII complex toward Di(p-nitrophenyl) phosphate: A functional model of heterobimetallic phosphodiestelase

Hironobu Machinaga; Kanako Matsufuji; Masaaki Ohba; Masahito Kodera; Hisashi Okawa

doi:10.1246/cl.2002.716

Hydrolytic activity of A Fe^IIIZn^II complex toward Di(p-nitrophenyl) phosphate: A functional model of heterobimetallic phosphodiestelase

Hironobu Machinaga, Kanako Matsufuji, Masaaki Ohba, Masahito Kodera, Hisashi Okawa

Inorganic and Analytical Chemistry

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

A Fe^IIIZn^III complex, [FeZn(L)(AcO)₃]BPh₄·H₂O, of 2-{N-[2-(dimethylamino)ethyl]iminomethyl}-6-[N, N-di(2-pyridyl-methyl)aminomethyl]-4-methylphenolate (L^-) hydrolyses tri(p-nitrophenyl) phosphate (TNP) into di(p-nitrophenyl) phosphate (DNP^-) and DNP^- into mono(p-nitrophenyl) phosphate (MNP^2-) in aqueous DMF.

Original language	English
Pages (from-to)	716-717
Number of pages	2
Journal	Chemistry Letters
Issue number	7
DOIs	https://doi.org/10.1246/cl.2002.716
Publication status	Published - Jul 5 2002

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Chemistry(all)

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title = "Hydrolytic activity of A FeIIIZnII complex toward Di(p-nitrophenyl) phosphate: A functional model of heterobimetallic phosphodiestelase",

abstract = "A FeIIIZnIII complex, [FeZn(L)(AcO)3]BPh4·H2O, of 2-{N-[2-(dimethylamino)ethyl]iminomethyl}-6-[N, N-di(2-pyridyl-methyl)aminomethyl]-4-methylphenolate (L-) hydrolyses tri(p-nitrophenyl) phosphate (TNP) into di(p-nitrophenyl) phosphate (DNP-) and DNP- into mono(p-nitrophenyl) phosphate (MNP2-) in aqueous DMF.",

author = "Hironobu Machinaga and Kanako Matsufuji and Masaaki Ohba and Masahito Kodera and Hisashi Okawa",

year = "2002",

month = jul,

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doi = "10.1246/cl.2002.716",

language = "English",

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journal = "Chemistry Letters",

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T1 - Hydrolytic activity of A FeIIIZnII complex toward Di(p-nitrophenyl) phosphate

T2 - A functional model of heterobimetallic phosphodiestelase

AU - Machinaga, Hironobu

AU - Matsufuji, Kanako

AU - Ohba, Masaaki

AU - Kodera, Masahito

AU - Okawa, Hisashi

PY - 2002/7/5

Y1 - 2002/7/5

N2 - A FeIIIZnIII complex, [FeZn(L)(AcO)3]BPh4·H2O, of 2-{N-[2-(dimethylamino)ethyl]iminomethyl}-6-[N, N-di(2-pyridyl-methyl)aminomethyl]-4-methylphenolate (L-) hydrolyses tri(p-nitrophenyl) phosphate (TNP) into di(p-nitrophenyl) phosphate (DNP-) and DNP- into mono(p-nitrophenyl) phosphate (MNP2-) in aqueous DMF.

AB - A FeIIIZnIII complex, [FeZn(L)(AcO)3]BPh4·H2O, of 2-{N-[2-(dimethylamino)ethyl]iminomethyl}-6-[N, N-di(2-pyridyl-methyl)aminomethyl]-4-methylphenolate (L-) hydrolyses tri(p-nitrophenyl) phosphate (TNP) into di(p-nitrophenyl) phosphate (DNP-) and DNP- into mono(p-nitrophenyl) phosphate (MNP2-) in aqueous DMF.

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JF - Chemistry Letters

IS - 7

ER -

Hydrolytic activity of A Fe^IIIZn^II complex toward Di(p-nitrophenyl) phosphate: A functional model of heterobimetallic phosphodiestelase

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