Hydrolytic function of a hydroxo-ZnIIPbII complex toward tris-p-nitrophenyl phosphate: A functional model of heterobimetallic phosphatases

Masako Yamami, Hideki Furutachi, Takushi Yokoyama, Hisashi Okawa

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

A ZnIIPbII complex ZnPb(L)(H2O)2(ClO4)2 of a macrocyclic compartmental ligand L2- is converted under alkaline conditions into a hydroxo complex ZnPb(L)(OH)(H2O)ClO4 that hydrolyzes tris-p-nitrophenyl phosphate (TNP) to bis-p-nitrophenyl phosphate (BNP-) forming a BNP-bridged complex [ZnPb(L)(BNP)]ClO4.

Original languageEnglish
Pages (from-to)211-212
Number of pages2
JournalChemistry Letters
Issue number3
DOIs
Publication statusPublished - Jan 1 1998

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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