TY - JOUR
T1 - Hydrosilane reduction of tertiary carboxamides by iron carbonyl catalysts
AU - Sunada, Yusuke
AU - Kawakami, Hiroko
AU - Imaoka, Tsuyoshi
AU - Motoyama, Yukihiro
AU - Nagashima, Hideo
PY - 2009/12/7
Y1 - 2009/12/7
N2 - Fox in the carboxamide: Reduction of tertiary carboxamides to their corresponding amines is catalyzed by [Fe(CO)5] or [Fe 3(CO)12], using 1,1,3,3tetramethyldlsiloxane (TMDS) as the reducing agent. The reaction proceeds under either thermal or photochemical conditions. Unlike the hydrosilane reduction of amides using platinum or ruthenlum catalysts, TMDS preferentially reduces a nitro group, even in the presence of competing amides.
AB - Fox in the carboxamide: Reduction of tertiary carboxamides to their corresponding amines is catalyzed by [Fe(CO)5] or [Fe 3(CO)12], using 1,1,3,3tetramethyldlsiloxane (TMDS) as the reducing agent. The reaction proceeds under either thermal or photochemical conditions. Unlike the hydrosilane reduction of amides using platinum or ruthenlum catalysts, TMDS preferentially reduces a nitro group, even in the presence of competing amides.
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U2 - 10.1002/anie.200905025
DO - 10.1002/anie.200905025
M3 - Article
C2 - 19904789
AN - SCOPUS:73249147403
SN - 1433-7851
VL - 48
SP - 9511
EP - 9514
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 50
ER -