Hydrotalcite-dispersed paper-structured catalyst for the dry reforming of methane

Yusuke Shiratori, M. Sakamoto, T. Uchida, H. Le, T. Quang-Tuyen, Kazunari Sasaki

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

A paper-structured catalyst (PSC) is a flexible planar catalyst that can be stacked on the anode of SOFCs and exhibits excellent catalytic activity for the reforming of hydrocarbon fuels at the operating temperature of the SOFC. Although our final goal is the realization of direct internal reforming (DIR) SOFCs fueled by biogas by applying a PSC, the tolerance of PSCs to sulfur impurities in biogas (H2S) must be improved for the practical application of PSCs to DIR-SOFCs operated by biogas. In this study, an inorganic fiber network in which a layered double hydroxide (Mg/Al-hydrotalcite denoted as HT) is dispersed was prepared by a paper-making process, and Ni was then loaded in this paper matrix via an impregnation process. This Ni-loaded HT-dispersed PSC exhibited considerably higher tolerance to H2S than that of HT-free PSC.

Original languageEnglish
Pages (from-to)10807-10815
Number of pages9
JournalInternational Journal of Hydrogen Energy
Volume40
Issue number34
DOIs
Publication statusPublished - Sep 14 2015

Fingerprint

Reforming reactions
Methane
Solid oxide fuel cells (SOFC)
methane
Biogas
catalysts
Catalysts
hydrocarbon fuels
operating temperature
Impregnation
hydroxides
catalytic activity
Catalyst activity
Anodes
anodes
sulfur
Sulfur
Hydrocarbons
Impurities
impurities

All Science Journal Classification (ASJC) codes

  • Renewable Energy, Sustainability and the Environment
  • Fuel Technology
  • Condensed Matter Physics
  • Energy Engineering and Power Technology

Cite this

Hydrotalcite-dispersed paper-structured catalyst for the dry reforming of methane. / Shiratori, Yusuke; Sakamoto, M.; Uchida, T.; Le, H.; Quang-Tuyen, T.; Sasaki, Kazunari.

In: International Journal of Hydrogen Energy, Vol. 40, No. 34, 14.09.2015, p. 10807-10815.

Research output: Contribution to journalArticle

Shiratori, Yusuke ; Sakamoto, M. ; Uchida, T. ; Le, H. ; Quang-Tuyen, T. ; Sasaki, Kazunari. / Hydrotalcite-dispersed paper-structured catalyst for the dry reforming of methane. In: International Journal of Hydrogen Energy. 2015 ; Vol. 40, No. 34. pp. 10807-10815.
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