Immobilization of a binuclear ruthenium(III) complex on a gold (111) surface: Observations of proton-coupled electron transfer and electrochemical durability in aqueous media

Hiromitsu Uehara; Masaaki Abe; Yoshio Hisaeda; Kohei Uosaki; Yoichi Sasaki

doi:10.1246/cl.2006.1178

Immobilization of a binuclear ruthenium(III) complex on a gold (111) surface: Observations of proton-coupled electron transfer and electrochemical durability in aqueous media

Hiromitsu Uehara, Masaaki Abe, Yoshio Hisaeda, Kohei Uosaki, Yoichi Sasaki

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

An oxo-bridged diruthenium(III) complex was immobilized on a Au(111) electrode through the coordination by terminal pyridyl groups of self-assembled monolayer of alkyl chains, and the immobilized complex underwent proton-coupled electron-transfer reactions in a very wide pH range (2-12) with remarkable monolayer durability for multiple potential cycles.

Original language	English
Pages (from-to)	1178-1179
Number of pages	2
Journal	Chemistry Letters
Volume	35
Issue number	10
DOIs	https://doi.org/10.1246/cl.2006.1178
Publication status	Published - Oct 5 2006

All Science Journal Classification (ASJC) codes

Chemistry(all)

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10.1246/cl.2006.1178

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abstract = "An oxo-bridged diruthenium(III) complex was immobilized on a Au(111) electrode through the coordination by terminal pyridyl groups of self-assembled monolayer of alkyl chains, and the immobilized complex underwent proton-coupled electron-transfer reactions in a very wide pH range (2-12) with remarkable monolayer durability for multiple potential cycles.",

author = "Hiromitsu Uehara and Masaaki Abe and Yoshio Hisaeda and Kohei Uosaki and Yoichi Sasaki",

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AU - Hisaeda, Yoshio

AU - Uosaki, Kohei

AU - Sasaki, Yoichi

PY - 2006/10/5

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AB - An oxo-bridged diruthenium(III) complex was immobilized on a Au(111) electrode through the coordination by terminal pyridyl groups of self-assembled monolayer of alkyl chains, and the immobilized complex underwent proton-coupled electron-transfer reactions in a very wide pH range (2-12) with remarkable monolayer durability for multiple potential cycles.

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Immobilization of a binuclear ruthenium(III) complex on a gold (111) surface: Observations of proton-coupled electron transfer and electrochemical durability in aqueous media

Abstract

All Science Journal Classification (ASJC) codes

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