Immobilization of a binuclear ruthenium(III) complex on a gold (111) surface: Observations of proton-coupled electron transfer and electrochemical durability in aqueous media

Hiromitsu Uehara, Masaaki Abe, Yoshio Hisaeda, Kohei Uosaki, Yoichi Sasaki

Research output: Contribution to journalArticlepeer-review

13 Citations (Scopus)

Abstract

An oxo-bridged diruthenium(III) complex was immobilized on a Au(111) electrode through the coordination by terminal pyridyl groups of self-assembled monolayer of alkyl chains, and the immobilized complex underwent proton-coupled electron-transfer reactions in a very wide pH range (2-12) with remarkable monolayer durability for multiple potential cycles.

Original languageEnglish
Pages (from-to)1178-1179
Number of pages2
JournalChemistry Letters
Volume35
Issue number10
DOIs
Publication statusPublished - Oct 5 2006

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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