Immobilization of asymmetric multifunctional catalysts on an insoluble polymer

S. Matsunaga; T. Ohshima; M. Shibasaki

doi:10.1016/S0040-4039(00)01486-6

Immobilization of asymmetric multifunctional catalysts on an insoluble polymer

S. Matsunaga, T. Ohshima, M. Shibasaki

Research output: Contribution to journal › Article › peer-review

85 Citations (Scopus)

Abstract

Polymer-supported linked-BINOL was synthesized to immobilize asymmetric catalysts with two BINOL units. The advantage of the polymer-supported linked-BINOL over randomly polymer-supported BINOL was confirmed by asymmetric Michael reaction. A novel polymer-supported La-Zn-linked-BINOL complex afforded the Michael adduct in good yield and moderate ee. (C) 2000 Elsevier Science Ltd.

Original language	English
Pages (from-to)	8473-8478
Number of pages	6
Journal	Tetrahedron Letters
Volume	41
Issue number	44
DOIs	https://doi.org/10.1016/S0040-4039(00)01486-6
Publication status	Published - Oct 28 2000
Externally published	Yes

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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title = "Immobilization of asymmetric multifunctional catalysts on an insoluble polymer",

abstract = "Polymer-supported linked-BINOL was synthesized to immobilize asymmetric catalysts with two BINOL units. The advantage of the polymer-supported linked-BINOL over randomly polymer-supported BINOL was confirmed by asymmetric Michael reaction. A novel polymer-supported La-Zn-linked-BINOL complex afforded the Michael adduct in good yield and moderate ee. (C) 2000 Elsevier Science Ltd.",

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AU - Ohshima, T.

AU - Shibasaki, M.

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N2 - Polymer-supported linked-BINOL was synthesized to immobilize asymmetric catalysts with two BINOL units. The advantage of the polymer-supported linked-BINOL over randomly polymer-supported BINOL was confirmed by asymmetric Michael reaction. A novel polymer-supported La-Zn-linked-BINOL complex afforded the Michael adduct in good yield and moderate ee. (C) 2000 Elsevier Science Ltd.

AB - Polymer-supported linked-BINOL was synthesized to immobilize asymmetric catalysts with two BINOL units. The advantage of the polymer-supported linked-BINOL over randomly polymer-supported BINOL was confirmed by asymmetric Michael reaction. A novel polymer-supported La-Zn-linked-BINOL complex afforded the Michael adduct in good yield and moderate ee. (C) 2000 Elsevier Science Ltd.

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