Immobilization of asymmetric multifunctional catalysts on an insoluble polymer

S. Matsunaga, T. Ohshima, M. Shibasaki

Research output: Contribution to journalArticlepeer-review

85 Citations (Scopus)

Abstract

Polymer-supported linked-BINOL was synthesized to immobilize asymmetric catalysts with two BINOL units. The advantage of the polymer-supported linked-BINOL over randomly polymer-supported BINOL was confirmed by asymmetric Michael reaction. A novel polymer-supported La-Zn-linked-BINOL complex afforded the Michael adduct in good yield and moderate ee. (C) 2000 Elsevier Science Ltd.

Original languageEnglish
Pages (from-to)8473-8478
Number of pages6
JournalTetrahedron Letters
Volume41
Issue number44
DOIs
Publication statusPublished - Oct 28 2000
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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