Immobilization of asymmetric multifunctional catalysts on an insoluble polymer

S. Matsunaga, T. Ohshima, M. Shibasaki

Research output: Contribution to journalArticle

84 Citations (Scopus)

Abstract

Polymer-supported linked-BINOL was synthesized to immobilize asymmetric catalysts with two BINOL units. The advantage of the polymer-supported linked-BINOL over randomly polymer-supported BINOL was confirmed by asymmetric Michael reaction. A novel polymer-supported La-Zn-linked-BINOL complex afforded the Michael adduct in good yield and moderate ee. (C) 2000 Elsevier Science Ltd.

Original languageEnglish
Pages (from-to)8473-8478
Number of pages6
JournalTetrahedron Letters
Volume41
Issue number44
DOIs
Publication statusPublished - Oct 28 2000

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Immobilization
Polymers
Catalysts
naphthol BINOL

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

Immobilization of asymmetric multifunctional catalysts on an insoluble polymer. / Matsunaga, S.; Ohshima, T.; Shibasaki, M.

In: Tetrahedron Letters, Vol. 41, No. 44, 28.10.2000, p. 8473-8478.

Research output: Contribution to journalArticle

Matsunaga, S. ; Ohshima, T. ; Shibasaki, M. / Immobilization of asymmetric multifunctional catalysts on an insoluble polymer. In: Tetrahedron Letters. 2000 ; Vol. 41, No. 44. pp. 8473-8478.
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