Immobilization of asymmetric multifunctional catalysts on an insoluble polymer

S. Matsunaga; T. Ohshima; M. Shibasaki

doi:10.1016/S0040-4039(00)01486-6

Immobilization of asymmetric multifunctional catalysts on an insoluble polymer

S. Matsunaga, T. Ohshima, M. Shibasaki

Research output: Contribution to journal › Article › peer-review

86 Citations (Scopus)

Abstract

Polymer-supported linked-BINOL was synthesized to immobilize asymmetric catalysts with two BINOL units. The advantage of the polymer-supported linked-BINOL over randomly polymer-supported BINOL was confirmed by asymmetric Michael reaction. A novel polymer-supported La-Zn-linked-BINOL complex afforded the Michael adduct in good yield and moderate ee. (C) 2000 Elsevier Science Ltd.

Original language	English
Pages (from-to)	8473-8478
Number of pages	6
Journal	Tetrahedron Letters
Volume	41
Issue number	44
DOIs	https://doi.org/10.1016/S0040-4039(00)01486-6
Publication status	Published - Oct 28 2000
Externally published	Yes

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(00)01486-6

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title = "Immobilization of asymmetric multifunctional catalysts on an insoluble polymer",

abstract = "Polymer-supported linked-BINOL was synthesized to immobilize asymmetric catalysts with two BINOL units. The advantage of the polymer-supported linked-BINOL over randomly polymer-supported BINOL was confirmed by asymmetric Michael reaction. A novel polymer-supported La-Zn-linked-BINOL complex afforded the Michael adduct in good yield and moderate ee. (C) 2000 Elsevier Science Ltd.",

author = "S. Matsunaga and T. Ohshima and M. Shibasaki",

note = "Funding Information: This work was supported by CREST and RFTF. S.M. thanks the JSPS Research Fellowships for Young Scientists. ",

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T1 - Immobilization of asymmetric multifunctional catalysts on an insoluble polymer

AU - Matsunaga, S.

AU - Ohshima, T.

AU - Shibasaki, M.

N1 - Funding Information: This work was supported by CREST and RFTF. S.M. thanks the JSPS Research Fellowships for Young Scientists.

PY - 2000/10/28

Y1 - 2000/10/28

N2 - Polymer-supported linked-BINOL was synthesized to immobilize asymmetric catalysts with two BINOL units. The advantage of the polymer-supported linked-BINOL over randomly polymer-supported BINOL was confirmed by asymmetric Michael reaction. A novel polymer-supported La-Zn-linked-BINOL complex afforded the Michael adduct in good yield and moderate ee. (C) 2000 Elsevier Science Ltd.

AB - Polymer-supported linked-BINOL was synthesized to immobilize asymmetric catalysts with two BINOL units. The advantage of the polymer-supported linked-BINOL over randomly polymer-supported BINOL was confirmed by asymmetric Michael reaction. A novel polymer-supported La-Zn-linked-BINOL complex afforded the Michael adduct in good yield and moderate ee. (C) 2000 Elsevier Science Ltd.

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U2 - 10.1016/S0040-4039(00)01486-6

DO - 10.1016/S0040-4039(00)01486-6

M3 - Article

AN - SCOPUS:0034727313

VL - 41

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EP - 8478

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 44

ER -

Immobilization of asymmetric multifunctional catalysts on an insoluble polymer

Abstract

All Science Journal Classification (ASJC) codes

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