Importance of steric bulkiness of iridium photocatalysts with PNNP tetradentate ligands for CO2 reduction

Kenji Kamada, Jieun Jung, Yohei Kametani, Taku Wakabayashi, Yoshihito Shiota, Kazunari Yoshizawa, Seong Hee Bae, Manami Muraki, Masayuki Naruto, Keita Sekizawa, Shunsuke Sato, Takeshi Morikawa, Susumu Saito

Research output: Contribution to journalArticlepeer-review

Abstract

A series of Ir complexes has been developed as multifunctional photocatalysts for CO2 reduction to give HCO2H selectively. The catalytic activities and photophysical properties vary widely across the series, and the bulky group insertion resulted in the formation of HCO2H and CO with the catalyst turnover number of >10 400.

Original languageEnglish
JournalChemical Communications
DOIs
Publication statusAccepted/In press - 2022

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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