Improved preparation of (η6-cycloheptatriene)-(η4-norbornadiene)ruthenium(0) and its reaction with acetylene

Hideo Nagashima; Hidenori Matsuda; Kenji Itoh

doi:10.1016/0022-328X(83)89518-7

Improved preparation of (η⁶-cycloheptatriene)-(η⁴-norbornadiene)ruthenium(0) and its reaction with acetylene

Hideo Nagashima, Hidenori Matsuda, Kenji Itoh

Research output: Contribution to journal › Article

29 Citations (Scopus)

Abstract

The complex (η⁶-cycloheptatriene)(η⁴-norbornadiene)ruthenium(O) is prepared efficiently by organometallic reduction of the readily available dichloro(η⁴-norbornadiene)dipyridineruthenium(II) followed by the addition of 1,3,5-cycloheptatriene. The ruthenium (O) complex reacted with acetylene to give (η⁶-bicyclo [4.2.1]nona-2,4,7-triene)(η⁴-norbornadiene)ruthenium(O) by formal [π6s+π2s]-cycloaddition.

Original language	English
Journal	Journal of Organometallic Chemistry
Volume	258
Issue number	1
DOIs	https://doi.org/10.1016/0022-328X(83)89518-7
Publication status	Published - Nov 22 1983
Externally published	Yes

Fingerprint

Acetylene

Ruthenium

acetylene

ruthenium

preparation

trienes

Cycloaddition

Cycloaddition Reaction

cycloaddition

Organometallics

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

Cite this

Nagashima, H., Matsuda, H., & Itoh, K. (1983). Improved preparation of (η⁶-cycloheptatriene)-(η⁴-norbornadiene)ruthenium(0) and its reaction with acetylene. Journal of Organometallic Chemistry, 258(1). https://doi.org/10.1016/0022-328X(83)89518-7

Improved preparation of (η⁶-cycloheptatriene)-(η⁴-norbornadiene)ruthenium(0) and its reaction with acetylene. / Nagashima, Hideo; Matsuda, Hidenori; Itoh, Kenji.

In: Journal of Organometallic Chemistry, Vol. 258, No. 1, 22.11.1983.

Research output: Contribution to journal › Article

Nagashima, H, Matsuda, H & Itoh, K 1983, 'Improved preparation of (η⁶-cycloheptatriene)-(η⁴-norbornadiene)ruthenium(0) and its reaction with acetylene', Journal of Organometallic Chemistry, vol. 258, no. 1. https://doi.org/10.1016/0022-328X(83)89518-7

Nagashima H, Matsuda H, Itoh K. Improved preparation of (η⁶-cycloheptatriene)-(η⁴-norbornadiene)ruthenium(0) and its reaction with acetylene. Journal of Organometallic Chemistry. 1983 Nov 22;258(1). https://doi.org/10.1016/0022-328X(83)89518-7

Nagashima, Hideo ; Matsuda, Hidenori ; Itoh, Kenji. / Improved preparation of (η⁶-cycloheptatriene)-(η⁴-norbornadiene)ruthenium(0) and its reaction with acetylene. In: Journal of Organometallic Chemistry. 1983 ; Vol. 258, No. 1.

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10.1016/0022-328X(83)89518-7