Improved preparation of (η6-cycloheptatriene)-(η4-norbornadiene)ruthenium(0) and its reaction with acetylene

Hideo Nagashima, Hidenori Matsuda, Kenji Itoh

Research output: Contribution to journalArticle

29 Citations (Scopus)

Abstract

The complex (η6-cycloheptatriene)(η4-norbornadiene)ruthenium(O) is prepared efficiently by organometallic reduction of the readily available dichloro(η4-norbornadiene)dipyridineruthenium(II) followed by the addition of 1,3,5-cycloheptatriene. The ruthenium (O) complex reacted with acetylene to give (η6-bicyclo [4.2.1]nona-2,4,7-triene)(η4-norbornadiene)ruthenium(O) by formal [π6s+π2s]-cycloaddition.

Original languageEnglish
JournalJournal of Organometallic Chemistry
Volume258
Issue number1
DOIs
Publication statusPublished - Nov 22 1983
Externally publishedYes

Fingerprint

Acetylene
Ruthenium
acetylene
ruthenium
preparation
trienes
Cycloaddition
Cycloaddition Reaction
cycloaddition
Organometallics

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

Improved preparation of (η6-cycloheptatriene)-(η4-norbornadiene)ruthenium(0) and its reaction with acetylene. / Nagashima, Hideo; Matsuda, Hidenori; Itoh, Kenji.

In: Journal of Organometallic Chemistry, Vol. 258, No. 1, 22.11.1983.

Research output: Contribution to journalArticle

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