TY - JOUR
T1 - Improved preparation of (η6-cycloheptatriene)-(η4-norbornadiene)ruthenium(0) and its reaction with acetylene
AU - Nagashima, Hideo
AU - Matsuda, Hidenori
AU - Itoh, Kenji
N1 - Funding Information:
Acknowledgement. Experimental assistance by Mr. M. Ichikawa is acknowledged. One of the authors (K.I.) is indebted to the Ministry of Education, Science and Culture, for a Grant-In-Aid for Scientific research (No. 58210014) and to Mitsubishi Chemical Industry Co. Ltd. for financial support.
PY - 1983/11/22
Y1 - 1983/11/22
N2 - The complex (η6-cycloheptatriene)(η4-norbornadiene)ruthenium(O) is prepared efficiently by organometallic reduction of the readily available dichloro(η4-norbornadiene)dipyridineruthenium(II) followed by the addition of 1,3,5-cycloheptatriene. The ruthenium (O) complex reacted with acetylene to give (η6-bicyclo [4.2.1]nona-2,4,7-triene)(η4-norbornadiene)ruthenium(O) by formal [π6s+π2s]-cycloaddition.
AB - The complex (η6-cycloheptatriene)(η4-norbornadiene)ruthenium(O) is prepared efficiently by organometallic reduction of the readily available dichloro(η4-norbornadiene)dipyridineruthenium(II) followed by the addition of 1,3,5-cycloheptatriene. The ruthenium (O) complex reacted with acetylene to give (η6-bicyclo [4.2.1]nona-2,4,7-triene)(η4-norbornadiene)ruthenium(O) by formal [π6s+π2s]-cycloaddition.
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U2 - 10.1016/0022-328X(83)89518-7
DO - 10.1016/0022-328X(83)89518-7
M3 - Article
AN - SCOPUS:0000438692
VL - 258
SP - C15-C18
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
SN - 0022-328X
IS - 1
ER -