Abstract
The complex (η6-cycloheptatriene)(η4-norbornadiene)ruthenium(O) is prepared efficiently by organometallic reduction of the readily available dichloro(η4-norbornadiene)dipyridineruthenium(II) followed by the addition of 1,3,5-cycloheptatriene. The ruthenium (O) complex reacted with acetylene to give (η6-bicyclo [4.2.1]nona-2,4,7-triene)(η4-norbornadiene)ruthenium(O) by formal [π6s+π2s]-cycloaddition.
| Original language | English |
|---|---|
| Pages (from-to) | C15-C18 |
| Journal | Journal of Organometallic Chemistry |
| Volume | 258 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - Nov 22 1983 |
| Externally published | Yes |
All Science Journal Classification (ASJC) codes
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
- Materials Chemistry
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Cite this
Nagashima, H., Matsuda, H., & Itoh, K. (1983). Improved preparation of (η6-cycloheptatriene)-(η4-norbornadiene)ruthenium(0) and its reaction with acetylene. Journal of Organometallic Chemistry, 258(1), C15-C18. https://doi.org/10.1016/0022-328X(83)89518-7