Improvement of the performance of fuel cells anodes with Sm3+ ddoped CeO2 interlayer

Shi Zhong Wang, Tatsumi Ishihara

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

An interlayer of samaria doped ceria(SDC) was prepared between Ni-SDC composite electrode and LSGM (La0.9Sr0.1Ga 0.8Mg0.2O3) electrolyte using screen-printing method to improve the performance of Ni anodes. The effect of this interlayer on the performance of anode as well as the cell was studied using various electrochemical techniques. The results show that addition of the SDC interlayer reduced the anodic over-potential significantly, however, the ohmic resistance of the cell with an SDC interlayer increased, which leaded to a decrease of the power output. The electrochemical oxidation of H2 on Ni-SDC anodes was controlled by two processes, which corresponded to two arcs in the impedance spectra. The high frequency arc decreased with the addition of SDC interlayer, and could correspond to the electrochemical reaction at three-phase-boundary(TPB) or the transfer of oxygen ions from LSGM to SDC. The low frequency arc showed no dependency on the addition of SDC, and could be related to the adsorption and diffusion of H2 at the surface of electrode. The cells with an SDC interlayer showed much better stability compared with the cell using single layer anode, and the performance of the cell with Ni-SDC/SDC(1573 K) anode was higher than the cell with a single layer Ni-SDC anode after long time running.

Original languageEnglish
Pages (from-to)849-853
Number of pages5
JournalActa Physico - Chimica Sinica
Volume19
Issue number9
Publication statusPublished - Sep 1 2003
Externally publishedYes

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cell anodes
Cerium compounds
fuel cells
Fuel cells
interlayers
Anodes
anodes
cells
arcs
electrodes
electrochemical oxidation
oxygen ions
printing
electrolytes
impedance
low frequencies
Electrodes
adsorption
Acoustic impedance
composite materials

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry

Cite this

Improvement of the performance of fuel cells anodes with Sm3+ ddoped CeO2 interlayer. / Wang, Shi Zhong; Ishihara, Tatsumi.

In: Acta Physico - Chimica Sinica, Vol. 19, No. 9, 01.09.2003, p. 849-853.

Research output: Contribution to journalArticle

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