In-situ Li7La3Zr2O12/LiCoO 2 interface modification for advanced all-solid-state battery

Takehisa Kato, Tadashi Hamanaka, Kazuo Yamamoto, Tsukasa Hirayama, Fumihiro Sagane, Munekazu Motoyama, Yasutoshi Iriyama

Research output: Contribution to journalArticlepeer-review

186 Citations (Scopus)


The inherent high resistance of electrolyte/electrode interface in all-solid-state-lithium-secondary batteries (SSLB) poses a significant hurdle for the SSLB development. The interfacial resistivity between Li 7La3Zr2O12 (LLZ) and LiCoO 2 is decreased by introducing a thin Nb layer (∼10 nm) at this interface. The interface modification approach using a Nb interlayer dramatically improves the discharge capacity and rate capability of a SSLB.

Original languageEnglish
Pages (from-to)292-298
Number of pages7
JournalJournal of Power Sources
Publication statusPublished - Aug 15 2014
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Renewable Energy, Sustainability and the Environment
  • Energy Engineering and Power Technology
  • Physical and Theoretical Chemistry
  • Electrical and Electronic Engineering


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