In situ synthesis of volatile carbonyl complexes with short-lived nuclides

Julia Even, Dieter Ackermann, Masato Asai, Michael Block, Holger Brand, Antonio Di Nitto, Christoph E. Düllmann, Robert Eichler, Fangli Fan, Hiromitsu Haba, Willi Hartmann, Annett Hübner, Fritz P. Heßberger, Minqhiu Huang, Egon Jäger, Daiya Kaji, Jumpei Kanaya, Yusuke Kaneya, Jadambaa Khuyagbaatar, Birgit KindlerJens V. Kratz, Jörg Krier, Yuki Kudou, Nikolaus Kurz, Mustapha Laatiaoui, Bettina Lommel, Joachim Maurer, Sunao Miyashita, Kouji Morimoto, Kosuke Morita, Masashi Murakami, Yuichiro Nagame, Heino Nitsche, Kazuhiro Ooe, Zhi Qin, Tetsuya K. Sato, Matthias Schädel, Jutta Steiner, Takayuki Sumita, Mirei Takeyama, Kengo Tanaka, Atsushi Toyoshima, Kazuaki Tsukada, Andreas Türler, Ilya Usoltsev, Yasuo Wakabayashi, Yang Wang, Norbert Wiehl, Alexander Yakushev, Sayaka Yamaki

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

Rapid in situ formation of metal carbonyl complexes with short-lived nuclides has been demonstrated to be feasible with recoiling ions formed in nuclear fusion and fission reactions. These carbonyl complexes are highly volatile and can be transported rapidly in a gas-stream to counting or chemistry devices. This method was already successfully applied in the chemical investigation of the superheavy element seaborgium (Z = 106) and appears promising for various fields of nuclear research. In this article, we give an overview on the current status of metal carbonyl complex studies with short-lived d-element isotopes.

Original languageEnglish
Pages (from-to)2457-2466
Number of pages10
JournalJournal of Radioanalytical and Nuclear Chemistry
Volume303
Issue number3
DOIs
Publication statusPublished - Jan 1 2015

All Science Journal Classification (ASJC) codes

  • Analytical Chemistry
  • Nuclear Energy and Engineering
  • Radiology Nuclear Medicine and imaging
  • Pollution
  • Spectroscopy
  • Public Health, Environmental and Occupational Health
  • Health, Toxicology and Mutagenesis

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  • Cite this

    Even, J., Ackermann, D., Asai, M., Block, M., Brand, H., Di Nitto, A., Düllmann, C. E., Eichler, R., Fan, F., Haba, H., Hartmann, W., Hübner, A., Heßberger, F. P., Huang, M., Jäger, E., Kaji, D., Kanaya, J., Kaneya, Y., Khuyagbaatar, J., ... Yamaki, S. (2015). In situ synthesis of volatile carbonyl complexes with short-lived nuclides. Journal of Radioanalytical and Nuclear Chemistry, 303(3), 2457-2466. https://doi.org/10.1007/s10967-014-3793-7