In situ tetrazole templated chair-like decanuclear azido-cobalt(ii) SMM containing both tetra- and octa-hedral Co(ii) ions

Yuan Zhu Zhang; Song Gao; Osamu Sato

doi:10.1039/c4dt03211j

In situ tetrazole templated chair-like decanuclear azido-cobalt(ii) SMM containing both tetra- and octa-hedral Co(ii) ions

Yuan Zhu Zhang, Song Gao, Osamu Sato

Department of Fundamental Organic Chemistry

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

An azido-bridged chair-like decanuclear cluster: [Co^II₁₀(bzp)₈(Metz)₂(N₃)₁₈]·4MeOH·3H₂O (1, bzp = 2-benzoylpyridine and HMetz = 5-methyl-1H-tetrazole) was prepared with in situ tetrazolate anions as templates in a sealed system. 1 containing both octahedral and tetrahedral Co(ii) ions exhibited slow relaxation of magnetization with an effective barrier of 26 K under an applied dc field of 1 kOe. This journal is

Original language	English
Pages (from-to)	480-483
Number of pages	4
Journal	Dalton Transactions
Volume	44
Issue number	2
DOIs	https://doi.org/10.1039/c4dt03211j
Publication status	Published - Jan 14 2015

All Science Journal Classification (ASJC) codes

Inorganic Chemistry

Access to Document

10.1039/c4dt03211j

Cite this

@article{c5c0ff7fc7fe4a16a709915e18341907,

title = "In situ tetrazole templated chair-like decanuclear azido-cobalt(ii) SMM containing both tetra- and octa-hedral Co(ii) ions",

abstract = "An azido-bridged chair-like decanuclear cluster: [CoII10(bzp)8(Metz)2(N3)18]·4MeOH·3H2O (1, bzp = 2-benzoylpyridine and HMetz = 5-methyl-1H-tetrazole) was prepared with in situ tetrazolate anions as templates in a sealed system. 1 containing both octahedral and tetrahedral Co(ii) ions exhibited slow relaxation of magnetization with an effective barrier of 26 K under an applied dc field of 1 kOe. This journal is",

author = "Zhang, {Yuan Zhu} and Song Gao and Osamu Sato",

year = "2015",

month = jan,

day = "14",

doi = "10.1039/c4dt03211j",

language = "English",

volume = "44",

pages = "480--483",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "2",

}

TY - JOUR

T1 - In situ tetrazole templated chair-like decanuclear azido-cobalt(ii) SMM containing both tetra- and octa-hedral Co(ii) ions

AU - Zhang, Yuan Zhu

AU - Gao, Song

AU - Sato, Osamu

PY - 2015/1/14

Y1 - 2015/1/14

N2 - An azido-bridged chair-like decanuclear cluster: [CoII10(bzp)8(Metz)2(N3)18]·4MeOH·3H2O (1, bzp = 2-benzoylpyridine and HMetz = 5-methyl-1H-tetrazole) was prepared with in situ tetrazolate anions as templates in a sealed system. 1 containing both octahedral and tetrahedral Co(ii) ions exhibited slow relaxation of magnetization with an effective barrier of 26 K under an applied dc field of 1 kOe. This journal is

AB - An azido-bridged chair-like decanuclear cluster: [CoII10(bzp)8(Metz)2(N3)18]·4MeOH·3H2O (1, bzp = 2-benzoylpyridine and HMetz = 5-methyl-1H-tetrazole) was prepared with in situ tetrazolate anions as templates in a sealed system. 1 containing both octahedral and tetrahedral Co(ii) ions exhibited slow relaxation of magnetization with an effective barrier of 26 K under an applied dc field of 1 kOe. This journal is

UR - http://www.scopus.com/inward/record.url?scp=84916613832&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84916613832&partnerID=8YFLogxK

U2 - 10.1039/c4dt03211j

DO - 10.1039/c4dt03211j

M3 - Article

AN - SCOPUS:84916613832

SN - 1477-9226

VL - 44

SP - 480

EP - 483

JO - Dalton Transactions

JF - Dalton Transactions

IS - 2

ER -

In situ tetrazole templated chair-like decanuclear azido-cobalt(ii) SMM containing both tetra- and octa-hedral Co(ii) ions

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this