In situ tetrazole templated chair-like decanuclear azido-cobalt(ii) SMM containing both tetra- and octa-hedral Co(ii) ions

Yuan Zhu Zhang, Song Gao, Osamu Sato

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

An azido-bridged chair-like decanuclear cluster: [CoII10(bzp)8(Metz)2(N3)18]·4MeOH·3H2O (1, bzp = 2-benzoylpyridine and HMetz = 5-methyl-1H-tetrazole) was prepared with in situ tetrazolate anions as templates in a sealed system. 1 containing both octahedral and tetrahedral Co(ii) ions exhibited slow relaxation of magnetization with an effective barrier of 26 K under an applied dc field of 1 kOe. This journal is

Original languageEnglish
Pages (from-to)480-483
Number of pages4
JournalDalton Transactions
Volume44
Issue number2
DOIs
Publication statusPublished - Jan 14 2015

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

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