@article{dae0aac4a5e4489380ebbad2fd39748b,
title = "Increased seebeck coefficient of [Fe(CN)6]41/31 thermocell based on the selective electrostatic interactions with cationic micelles",
abstract = "The Seebeck coefficient of a thermocell consisting of [Fe(CN)6]41/31 undergoes salient change from 11.43 to +3.5 mV K11 by the addition of dodecyl tetramethylammonium bromide (DTAB) micelles. This originates from the unexpected binding affinity of [Fe(CN)6]31 to DTAB micelles as compared to that of [Fe(CN)6]41, which was confirmed by spectroscopic and electrochemical measurements. This result provides a novel strategy for improving the Seebeck coefficient of versatile redox species by taking advantage of the amphiphilic ion-paring.",
author = "Risa Iwami and Teppei Yamada and Nobuo Kimizuka",
note = "Funding Information: This work was partly supported by JST PRESTO Grant Number JPMJPR141D, JSPS KAKENHI Grant Numbers JP25220805, JP17H03046, JP 20H02714, JP19H05061 (Hydrogenomics), JP16H06513 (Coordination Asymmetry). The authors would like to show our appreciation to the financial support from Ogasawara Foundation for the Promotion of Science & Engineering, ?Innovation inspired by Nature? Research Support Program, SEKISUI CHEMICAL CO. LTD and The Thermal & Electric Energy Technology Foundation.",
year = "2020",
doi = "10.1246/CL.200410",
language = "English",
volume = "49",
journal = "Chemistry Letters",
issn = "0366-7022",
publisher = "The Chemical Society of Japan",
number = "10",
}