Abstract
We demonstrate that domain structure of single-layer graphene grown by ambient pressure chemical vapor deposition is strongly dependent on the crystallinity of the Cu catalyst. Low energy electron microscopy analysis reveals that graphene grown using a Cu foil gives small and mis-oriented graphene domains with a number of domain boundaries. On the other hand, no apparent domain boundaries are observed in graphene grown over a heteroepitaxial Cu(111) film deposited on sapphire due to unified orientation of graphene hexagons. The difference in the domain structures is correlated with the difference in the crystal plane and grain structure of the Cu metal. The graphene film grown on the heteroepitaxial Cu film exhibits much higher carrier mobility than that grown on the Cu foil.
Original language | English |
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Pages (from-to) | 2189-2196 |
Number of pages | 8 |
Journal | Carbon |
Volume | 50 |
Issue number | 6 |
DOIs | |
Publication status | Published - May 2012 |
All Science Journal Classification (ASJC) codes
- Chemistry(all)
- Materials Science(all)