Influence of Mg2+ ion on the reduction of N-methylacridinium ion with 1,4-dihydronicotinamide

Seiji Shinkai; Toyoko Ide; Hisatake Hamada; Osamu Manabe; Toyoki Kunitake

doi:10.1039/C39770000848

Influence of Mg²⁺ ion on the reduction of N-methylacridinium ion with 1,4-dihydronicotinamide

Seiji Shinkai, Toyoko Ide, Hisatake Hamada, Osamu Manabe, Toyoki Kunitake

Research output: Contribution to journal › Article › peer-review

33 Citations (Scopus)

Abstract

The reaction of N-benzyl-1,4-dihydronicotinamide and N-methylacridinium ion in the presence of Mg²⁺ gives a normal secondary isotope effect (k_H/k_H′ = 0·98 ± 0·04) and an identical value (3·7) for the primary isotope effect (k _H/k_D) and the isotopic partitioning ratio.

Original language	English
Pages (from-to)	848-849
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	23
DOIs	https://doi.org/10.1039/C39770000848
Publication status	Published - Dec 1 1977
Externally published	Yes

All Science Journal Classification (ASJC) codes

Molecular Medicine

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title = "Influence of Mg2+ ion on the reduction of N-methylacridinium ion with 1,4-dihydronicotinamide",

abstract = "The reaction of N-benzyl-1,4-dihydronicotinamide and N-methylacridinium ion in the presence of Mg2+ gives a normal secondary isotope effect (kH/kH′ = 0·98 ± 0·04) and an identical value (3·7) for the primary isotope effect (k H/kD) and the isotopic partitioning ratio.",

author = "Seiji Shinkai and Toyoko Ide and Hisatake Hamada and Osamu Manabe and Toyoki Kunitake",

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T1 - Influence of Mg2+ ion on the reduction of N-methylacridinium ion with 1,4-dihydronicotinamide

AU - Shinkai, Seiji

AU - Ide, Toyoko

AU - Hamada, Hisatake

AU - Manabe, Osamu

AU - Kunitake, Toyoki

PY - 1977/12/1

Y1 - 1977/12/1

N2 - The reaction of N-benzyl-1,4-dihydronicotinamide and N-methylacridinium ion in the presence of Mg2+ gives a normal secondary isotope effect (kH/kH′ = 0·98 ± 0·04) and an identical value (3·7) for the primary isotope effect (k H/kD) and the isotopic partitioning ratio.

AB - The reaction of N-benzyl-1,4-dihydronicotinamide and N-methylacridinium ion in the presence of Mg2+ gives a normal secondary isotope effect (kH/kH′ = 0·98 ± 0·04) and an identical value (3·7) for the primary isotope effect (k H/kD) and the isotopic partitioning ratio.

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Influence of Mg²⁺ ion on the reduction of N-methylacridinium ion with 1,4-dihydronicotinamide

Abstract

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