Influence of the Au-S bond in the self-assembled monolayer of the helical peptides on gold

Takako Iizuka-Sakano, Katsuhiko Fujita, Takashi Isoshima, Tatsuo Wada, Hiroyuki Sasabe

Research output: Contribution to journalConference article

Abstract

We numerically investigate molecular arrangement and orientation in the self-assembled peptide monolayer adsorbed on gold considering dipoles of each amide group in peptides and a dipole due to the Au-S bond at the chemisorption site. We investigate a single peptide adsorbed on gold and SAM of two dimensional crystal. Comparing their results with that of ignoring Au-S dipole, we show that molecules can take an orientation standing normal to the surface by Au-S dipole.

Original languageEnglish
Pages (from-to)227-230
Number of pages4
JournalMolecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volume349
DOIs
Publication statusPublished - Jan 1 2000
EventProceedings of the Korea-Japan Joint Forum 1999 Organic Materials for Electronics and Photonics - Kyongju, South Korea
Duration: Sep 9 1999Sep 11 1999

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Self assembled monolayers
Gold
Peptides
peptides
gold
dipoles
Chemisorption
Amides
Monolayers
chemisorption
amides
Crystals
Molecules
crystals
molecules

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics

Cite this

Influence of the Au-S bond in the self-assembled monolayer of the helical peptides on gold. / Iizuka-Sakano, Takako; Fujita, Katsuhiko; Isoshima, Takashi; Wada, Tatsuo; Sasabe, Hiroyuki.

In: Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, Vol. 349, 01.01.2000, p. 227-230.

Research output: Contribution to journalConference article

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