Infrared spectroscopy of molten LiCl-KCl-LiH

Hironori Nakajima, Toshiyuki Nohira, Yasuhiko Ito

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Infrared spectroscopy of molten LiCl-KCl-LiH at 673 K provided absorption band in the wavenumber region of 1400-1500 cm-1 for several H - ion concentrations. This absorption band is ascribed to the vibration of Li+-H- ion pair in the melt. The absorption band ascribed to the vibration of K+-H- ion pair was not observed in the melt. The existence of the Li-H interaction shows a strong attractive force between H- ion and Li+ ion in the melt.

Original languageEnglish
JournalElectrochemical and Solid-State Letters
Volume7
Issue number5
DOIs
Publication statusPublished - May 20 2004
Externally publishedYes

Fingerprint

Molten materials
Infrared spectroscopy
infrared spectroscopy
Ions
Absorption spectra
absorption spectra
ions
vibration
ion concentration
interactions

All Science Journal Classification (ASJC) codes

  • Chemical Engineering(all)
  • Materials Science(all)
  • Physical and Theoretical Chemistry
  • Electrochemistry
  • Electrical and Electronic Engineering

Cite this

Infrared spectroscopy of molten LiCl-KCl-LiH. / Nakajima, Hironori; Nohira, Toshiyuki; Ito, Yasuhiko.

In: Electrochemical and Solid-State Letters, Vol. 7, No. 5, 20.05.2004.

Research output: Contribution to journalArticle

Nakajima, Hironori ; Nohira, Toshiyuki ; Ito, Yasuhiko. / Infrared spectroscopy of molten LiCl-KCl-LiH. In: Electrochemical and Solid-State Letters. 2004 ; Vol. 7, No. 5.
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