Infrared spectroscopy of molten LiCl-KCl-LiH

Hironori Nakajima; Toshiyuki Nohira; Yasuhiko Ito

doi:10.1149/1.1664052

Infrared spectroscopy of molten LiCl-KCl-LiH

Hironori Nakajima, Toshiyuki Nohira, Yasuhiko Ito

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Infrared spectroscopy of molten LiCl-KCl-LiH at 673 K provided absorption band in the wavenumber region of 1400-1500 cm^-1 for several H ^- ion concentrations. This absorption band is ascribed to the vibration of Li⁺-H^- ion pair in the melt. The absorption band ascribed to the vibration of K⁺-H^- ion pair was not observed in the melt. The existence of the Li-H interaction shows a strong attractive force between H^- ion and Li⁺ ion in the melt.

Original language	English
Journal	Electrochemical and Solid-State Letters
Volume	7
Issue number	5
DOIs	https://doi.org/10.1149/1.1664052
Publication status	Published - May 20 2004
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemical Engineering(all)
Materials Science(all)
Physical and Theoretical Chemistry
Electrochemistry
Electrical and Electronic Engineering

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abstract = "Infrared spectroscopy of molten LiCl-KCl-LiH at 673 K provided absorption band in the wavenumber region of 1400-1500 cm-1 for several H - ion concentrations. This absorption band is ascribed to the vibration of Li+-H- ion pair in the melt. The absorption band ascribed to the vibration of K+-H- ion pair was not observed in the melt. The existence of the Li-H interaction shows a strong attractive force between H- ion and Li+ ion in the melt.",

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AU - Nakajima, Hironori

AU - Nohira, Toshiyuki

AU - Ito, Yasuhiko

PY - 2004/5/20

Y1 - 2004/5/20

N2 - Infrared spectroscopy of molten LiCl-KCl-LiH at 673 K provided absorption band in the wavenumber region of 1400-1500 cm-1 for several H - ion concentrations. This absorption band is ascribed to the vibration of Li+-H- ion pair in the melt. The absorption band ascribed to the vibration of K+-H- ion pair was not observed in the melt. The existence of the Li-H interaction shows a strong attractive force between H- ion and Li+ ion in the melt.

AB - Infrared spectroscopy of molten LiCl-KCl-LiH at 673 K provided absorption band in the wavenumber region of 1400-1500 cm-1 for several H - ion concentrations. This absorption band is ascribed to the vibration of Li+-H- ion pair in the melt. The absorption band ascribed to the vibration of K+-H- ion pair was not observed in the melt. The existence of the Li-H interaction shows a strong attractive force between H- ion and Li+ ion in the melt.

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JO - Electrochemical and Solid-State Letters

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ER -

Infrared spectroscopy of molten LiCl-KCl-LiH

Abstract

All Science Journal Classification (ASJC) codes

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