Abstract
Infrared spectroscopy of molten LiCl-KCl eutectic melt under several hydrogen pressures at 673 K provided an absorption band in the wavenumber region of 1300-1600 cm-1. This absorption band is ascribed to the vibration of a Li-H interaction in the melt. On the other hand, the absorption bands ascribed to a K-H interaction and H-Cl interaction were not observed. The existence of the Li-H interaction shows a strong attractive force between dissolved hydrogen atoms and Li+ ions in the melt.
| Original language | English |
|---|---|
| Pages (from-to) | 4567-4569 |
| Number of pages | 3 |
| Journal | Journal of Physical Chemistry A |
| Volume | 108 |
| Issue number | 21 |
| DOIs | |
| Publication status | Published - May 27 2004 |
| Externally published | Yes |
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All Science Journal Classification (ASJC) codes
- Physical and Theoretical Chemistry
Cite this
Infrared spectroscopy of molten LiCl-KCl under hydrogen gas atmosphere. / Nakajima, Hironori; Nohira, Toshiyuki; Ito, Yasuhiko.
In: Journal of Physical Chemistry A, Vol. 108, No. 21, 27.05.2004, p. 4567-4569.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Infrared spectroscopy of molten LiCl-KCl under hydrogen gas atmosphere
AU - Nakajima, Hironori
AU - Nohira, Toshiyuki
AU - Ito, Yasuhiko
PY - 2004/5/27
Y1 - 2004/5/27
N2 - Infrared spectroscopy of molten LiCl-KCl eutectic melt under several hydrogen pressures at 673 K provided an absorption band in the wavenumber region of 1300-1600 cm-1. This absorption band is ascribed to the vibration of a Li-H interaction in the melt. On the other hand, the absorption bands ascribed to a K-H interaction and H-Cl interaction were not observed. The existence of the Li-H interaction shows a strong attractive force between dissolved hydrogen atoms and Li+ ions in the melt.
AB - Infrared spectroscopy of molten LiCl-KCl eutectic melt under several hydrogen pressures at 673 K provided an absorption band in the wavenumber region of 1300-1600 cm-1. This absorption band is ascribed to the vibration of a Li-H interaction in the melt. On the other hand, the absorption bands ascribed to a K-H interaction and H-Cl interaction were not observed. The existence of the Li-H interaction shows a strong attractive force between dissolved hydrogen atoms and Li+ ions in the melt.
UR - http://www.scopus.com/inward/record.url?scp=2942625795&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=2942625795&partnerID=8YFLogxK
U2 - 10.1021/jp049490y
DO - 10.1021/jp049490y
M3 - Article
AN - SCOPUS:2942625795
VL - 108
SP - 4567
EP - 4569
JO - Journal of Physical Chemistry A
JF - Journal of Physical Chemistry A
SN - 1089-5639
IS - 21
ER -