Infrared spectroscopy of molten LiCl-KCl under hydrogen gas atmosphere

Hironori Nakajima, Toshiyuki Nohira, Yasuhiko Ito

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

Infrared spectroscopy of molten LiCl-KCl eutectic melt under several hydrogen pressures at 673 K provided an absorption band in the wavenumber region of 1300-1600 cm-1. This absorption band is ascribed to the vibration of a Li-H interaction in the melt. On the other hand, the absorption bands ascribed to a K-H interaction and H-Cl interaction were not observed. The existence of the Li-H interaction shows a strong attractive force between dissolved hydrogen atoms and Li+ ions in the melt.

Original languageEnglish
Pages (from-to)4567-4569
Number of pages3
JournalJournal of Physical Chemistry A
Volume108
Issue number21
DOIs
Publication statusPublished - May 27 2004
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry

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