Abstract
Infrared spectroscopy of molten LiCl-KCl eutectic melt under several hydrogen pressures at 673 K provided an absorption band in the wavenumber region of 1300-1600 cm-1. This absorption band is ascribed to the vibration of a Li-H interaction in the melt. On the other hand, the absorption bands ascribed to a K-H interaction and H-Cl interaction were not observed. The existence of the Li-H interaction shows a strong attractive force between dissolved hydrogen atoms and Li+ ions in the melt.
| Original language | English |
|---|---|
| Pages (from-to) | 4567-4569 |
| Number of pages | 3 |
| Journal | Journal of Physical Chemistry A |
| Volume | 108 |
| Issue number | 21 |
| DOIs | |
| Publication status | Published - May 27 2004 |
| Externally published | Yes |
All Science Journal Classification (ASJC) codes
- Physical and Theoretical Chemistry
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Cite this
Nakajima, H., Nohira, T., & Ito, Y. (2004). Infrared spectroscopy of molten LiCl-KCl under hydrogen gas atmosphere. Journal of Physical Chemistry A, 108(21), 4567-4569. https://doi.org/10.1021/jp049490y