Infrared spectroscopy of molten LiCl-KCl under hydrogen gas atmosphere

Hironori Nakajima; Toshiyuki Nohira; Yasuhiko Ito

doi:10.1021/jp049490y

Infrared spectroscopy of molten LiCl-KCl under hydrogen gas atmosphere

Hironori Nakajima, Toshiyuki Nohira, Yasuhiko Ito

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

Infrared spectroscopy of molten LiCl-KCl eutectic melt under several hydrogen pressures at 673 K provided an absorption band in the wavenumber region of 1300-1600 cm^-1. This absorption band is ascribed to the vibration of a Li-H interaction in the melt. On the other hand, the absorption bands ascribed to a K-H interaction and H-Cl interaction were not observed. The existence of the Li-H interaction shows a strong attractive force between dissolved hydrogen atoms and Li⁺ ions in the melt.

Original language	English
Pages (from-to)	4567-4569
Number of pages	3
Journal	Journal of Physical Chemistry A
Volume	108
Issue number	21
DOIs	https://doi.org/10.1021/jp049490y
Publication status	Published - May 27 2004
Externally published	Yes

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry

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10.1021/jp049490y

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title = "Infrared spectroscopy of molten LiCl-KCl under hydrogen gas atmosphere",

abstract = "Infrared spectroscopy of molten LiCl-KCl eutectic melt under several hydrogen pressures at 673 K provided an absorption band in the wavenumber region of 1300-1600 cm-1. This absorption band is ascribed to the vibration of a Li-H interaction in the melt. On the other hand, the absorption bands ascribed to a K-H interaction and H-Cl interaction were not observed. The existence of the Li-H interaction shows a strong attractive force between dissolved hydrogen atoms and Li+ ions in the melt.",

author = "Hironori Nakajima and Toshiyuki Nohira and Yasuhiko Ito",

year = "2004",

month = may,

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doi = "10.1021/jp049490y",

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journal = "Journal of Physical Chemistry A",

issn = "1089-5639",

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T1 - Infrared spectroscopy of molten LiCl-KCl under hydrogen gas atmosphere

AU - Nakajima, Hironori

AU - Nohira, Toshiyuki

AU - Ito, Yasuhiko

PY - 2004/5/27

Y1 - 2004/5/27

N2 - Infrared spectroscopy of molten LiCl-KCl eutectic melt under several hydrogen pressures at 673 K provided an absorption band in the wavenumber region of 1300-1600 cm-1. This absorption band is ascribed to the vibration of a Li-H interaction in the melt. On the other hand, the absorption bands ascribed to a K-H interaction and H-Cl interaction were not observed. The existence of the Li-H interaction shows a strong attractive force between dissolved hydrogen atoms and Li+ ions in the melt.

AB - Infrared spectroscopy of molten LiCl-KCl eutectic melt under several hydrogen pressures at 673 K provided an absorption band in the wavenumber region of 1300-1600 cm-1. This absorption band is ascribed to the vibration of a Li-H interaction in the melt. On the other hand, the absorption bands ascribed to a K-H interaction and H-Cl interaction were not observed. The existence of the Li-H interaction shows a strong attractive force between dissolved hydrogen atoms and Li+ ions in the melt.

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DO - 10.1021/jp049490y

M3 - Article

AN - SCOPUS:2942625795

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JO - Journal of Physical Chemistry A

JF - Journal of Physical Chemistry A

SN - 1089-5639

IS - 21

ER -

Infrared spectroscopy of molten LiCl-KCl under hydrogen gas atmosphere

Abstract

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