Infrared spectroscopy of molten LiCl-KCl under hydrogen gas atmosphere

Hironori Nakajima, Toshiyuki Nohira, Yasuhiko Ito

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

Infrared spectroscopy of molten LiCl-KCl eutectic melt under several hydrogen pressures at 673 K provided an absorption band in the wavenumber region of 1300-1600 cm-1. This absorption band is ascribed to the vibration of a Li-H interaction in the melt. On the other hand, the absorption bands ascribed to a K-H interaction and H-Cl interaction were not observed. The existence of the Li-H interaction shows a strong attractive force between dissolved hydrogen atoms and Li+ ions in the melt.

Original languageEnglish
Pages (from-to)4567-4569
Number of pages3
JournalJournal of Physical Chemistry A
Volume108
Issue number21
DOIs
Publication statusPublished - May 27 2004
Externally publishedYes

Fingerprint

Molten materials
Absorption spectra
Hydrogen
Infrared spectroscopy
Gases
infrared spectroscopy
atmospheres
hydrogen
absorption spectra
gases
interactions
Eutectics
eutectics
Ions
hydrogen atoms
Atoms
vibration
ions

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry

Cite this

Infrared spectroscopy of molten LiCl-KCl under hydrogen gas atmosphere. / Nakajima, Hironori; Nohira, Toshiyuki; Ito, Yasuhiko.

In: Journal of Physical Chemistry A, Vol. 108, No. 21, 27.05.2004, p. 4567-4569.

Research output: Contribution to journalArticle

Nakajima, Hironori ; Nohira, Toshiyuki ; Ito, Yasuhiko. / Infrared spectroscopy of molten LiCl-KCl under hydrogen gas atmosphere. In: Journal of Physical Chemistry A. 2004 ; Vol. 108, No. 21. pp. 4567-4569.
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