Inhibiting effects of trace amounts of lanthanum ion on the dissolution of calcite

A comparative study on calcium carbonate polymorphs

Natsumi Kamiya, Hiroyuki Kagi, Kenji Notsu, Hiroshi Tsuno, Tasuku Akagi

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

A significant inhibiting effect was observed on the dissolution of calcite by addition of 5 μM lanthanum ion to the solution, whereas no inhibition was observed both for aragonite and vaterite under the same conditions. In situ AFM (atomic force microscopy) images suggested that micro-precipitates depositing at the step site of calcite inhibited the dissolution in the lanthanum-doped solution. The solubility-calculation for the given solution was consistent with lanthanum carbonate being the micro-precipitate.

Original languageEnglish
Pages (from-to)890-891
Number of pages2
JournalChemistry Letters
Issue number9
DOIs
Publication statusPublished - Sep 5 2002
Externally publishedYes

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Lanthanum
Calcium Carbonate
Polymorphism
Dissolution
Ions
Precipitates
Atomic force microscopy
Solubility

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

Inhibiting effects of trace amounts of lanthanum ion on the dissolution of calcite : A comparative study on calcium carbonate polymorphs. / Kamiya, Natsumi; Kagi, Hiroyuki; Notsu, Kenji; Tsuno, Hiroshi; Akagi, Tasuku.

In: Chemistry Letters, No. 9, 05.09.2002, p. 890-891.

Research output: Contribution to journalArticle

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