Inorganic clusters with a [Fe2MoOS3] core - A functional model for acetylene reduction by nitrogenases

Koji Yoshimoto; Takeshi Yatabe; Takahiro Matsumoto; Viet Ha Tran; Andrew Robertson; Hidetaka Nakai; Koichiro Asazawa; Hirohisa Tanaka; Seiji Ogo

doi:10.1039/c6dt01655c

Inorganic clusters with a [Fe₂MoOS₃] core - A functional model for acetylene reduction by nitrogenases

Koji Yoshimoto, Takeshi Yatabe, Takahiro Matsumoto, Viet Ha Tran, Andrew Robertson, Hidetaka Nakai, Koichiro Asazawa, Hirohisa Tanaka, Seiji Ogo

Research output: Contribution to journal › Article

4 Citations (Scopus)

Abstract

We report the first example of a wholly inorganic mimic of a part of the FeMoco active centre of nitrogenases. We detail the synthesis, characterisation and reactivity of two related, transient hydride-containing inorganic clusters, a dihydride complex and a vinyl monohydride complex, which bear the [Fe₂MoOS₃] portion of FeMoco. The dihydride complex is capable of reducing acetylene to ethylene via the vinyl monohydride complex. In the reaction cycle, a transient low-valent complex was generated by the reductive elimination of H₂ or ethylene from dihydride or vinyl monohydride complexes, respectively.

Original language	English
Pages (from-to)	14620-14627
Number of pages	8
Journal	Dalton Transactions
Volume	45
Issue number	37
DOIs	https://doi.org/10.1039/c6dt01655c
Publication status	Published - Jan 1 2016

All Science Journal Classification (ASJC) codes

Inorganic Chemistry

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10.1039/c6dt01655c

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Yoshimoto, K., Yatabe, T., Matsumoto, T., Tran, V. H., Robertson, A., Nakai, H., Asazawa, K., Tanaka, H., & Ogo, S. (2016). Inorganic clusters with a [Fe₂MoOS₃] core - A functional model for acetylene reduction by nitrogenases. Dalton Transactions, 45(37), 14620-14627. https://doi.org/10.1039/c6dt01655c

Inorganic clusters with a [Fe₂MoOS₃] core - A functional model for acetylene reduction by nitrogenases. / Yoshimoto, Koji; Yatabe, Takeshi ; Matsumoto, Takahiro; Tran, Viet Ha; Robertson, Andrew; Nakai, Hidetaka; Asazawa, Koichiro; Tanaka, Hirohisa; Ogo, Seiji.

In: Dalton Transactions, Vol. 45, No. 37, 01.01.2016, p. 14620-14627.

Research output: Contribution to journal › Article

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