Insights into effects of O-incorporated Ag nanoparticles as wetting seeds toward improving Ag wetting on oxides

Guoqing Zhao, Eunwook Jeong, Sang Geul Lee, Seung Min Yu, Jong Seong Bae, Jongjoo Rha, Gun Hwan Lee, Yoshifumi Ikoma, Jungheum Yun

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

Ag wetting on oxides is essential for implementing exceptional layered Ag superstructures with simultaneous ultralow losses in electrical conductance and optical transmittance. This goal is difficult to achieve by conventional synthetic techniques involving the incorporation of heterogeneous transition metals or metalloids into Ag as wetting inducers as they cause detrimental optoelectrical changes. This study provides novel insights into the use of homogeneous Ag wetting seeds to improve the wetting of Ag on oxides. We investigated the effect of atomic O incorporation on the improvement of Ag wetting by monitoring its participation in and contribution to the Ag clustering and layering processes. Minimal incorporation of dissolved atomic O as a surfactant into the Ag nanoparticles transposed the nanoparticle evolution path from a complete to incomplete coalescence mode at significantly reduced thicknesses, which was attributed to a reduction in the nanoparticle free energy. The size and shape of the O-incorporated Ag nanoparticles were precisely controlled to accelerate the wetting transition of Ag on ZnO substrates by circumventing the transmutation effect of O. These results demonstrate a notable strategy for accomplishing a rapid Ag wetting transition toward a completely continuous layer with ultralow optoelectrical losses.

Original languageEnglish
Article number150135
JournalApplied Surface Science
Volume562
DOIs
Publication statusPublished - Oct 1 2021

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Condensed Matter Physics
  • Physics and Astronomy(all)
  • Surfaces and Interfaces
  • Surfaces, Coatings and Films

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