Intercalation-controlled cyclodehydration of sorbitol in water over layered-niobium-molybdate solid acid

Yuya Morita, Shogo Furusato, Atsushi Takagaki, Shigenobu Hayashi, Ryuji Kikuchi, S. Ted Oyama

Research output: Contribution to journalArticle

30 Citations (Scopus)

Abstract

Layered niobium molybdate (HNbMoO6) was used in the aqueous-phase dehydration of sorbitol and was found to exhibit remarkable selectivity toward its monomolecular-dehydrated intermediate 1,4-sorbitan. This was attributed to the selective intercalation of sorbitol within the interlayers with strong Brønsted acid sites. The power of intercalation: The aqueous-phase dehydration of a sugar alcohol, sorbitol, to its monomolecular dehydrated intermediate, 1,4-sorbitan, with high selectivity is described for the use of a unique solid acid, HNbMoO6. The activity and selectivity to 1,4-sorbitan is superior to those obtained on other solid acids, including protonic zeolites, niobic acid, and ion-exchange resins. This improvement is attributable to the control intercalation selectivity.

Original languageEnglish
Pages (from-to)748-752
Number of pages5
JournalChemSusChem
Volume7
Issue number3
DOIs
Publication statusPublished - Mar 1 2014
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Environmental Chemistry
  • Chemical Engineering(all)
  • Materials Science(all)
  • Energy(all)

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