Abstract
Layered niobium molybdate (HNbMoO6) was used in the aqueous-phase dehydration of sorbitol and was found to exhibit remarkable selectivity toward its monomolecular-dehydrated intermediate 1,4-sorbitan. This was attributed to the selective intercalation of sorbitol within the interlayers with strong Brønsted acid sites. The power of intercalation: The aqueous-phase dehydration of a sugar alcohol, sorbitol, to its monomolecular dehydrated intermediate, 1,4-sorbitan, with high selectivity is described for the use of a unique solid acid, HNbMoO6. The activity and selectivity to 1,4-sorbitan is superior to those obtained on other solid acids, including protonic zeolites, niobic acid, and ion-exchange resins. This improvement is attributable to the control intercalation selectivity.
| Original language | English |
|---|---|
| Pages (from-to) | 748-752 |
| Number of pages | 5 |
| Journal | ChemSusChem |
| Volume | 7 |
| Issue number | 3 |
| DOIs | |
| Publication status | Published - Mar 1 2014 |
| Externally published | Yes |
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All Science Journal Classification (ASJC) codes
- Environmental Chemistry
- Chemical Engineering(all)
- Materials Science(all)
- Energy(all)
Cite this
Intercalation-controlled cyclodehydration of sorbitol in water over layered-niobium-molybdate solid acid. / Morita, Yuya; Furusato, Shogo; Takagaki, Atsushi; Hayashi, Shigenobu; Kikuchi, Ryuji; Oyama, S. Ted.
In: ChemSusChem, Vol. 7, No. 3, 01.03.2014, p. 748-752.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Intercalation-controlled cyclodehydration of sorbitol in water over layered-niobium-molybdate solid acid
AU - Morita, Yuya
AU - Furusato, Shogo
AU - Takagaki, Atsushi
AU - Hayashi, Shigenobu
AU - Kikuchi, Ryuji
AU - Oyama, S. Ted
PY - 2014/3/1
Y1 - 2014/3/1
N2 - Layered niobium molybdate (HNbMoO6) was used in the aqueous-phase dehydration of sorbitol and was found to exhibit remarkable selectivity toward its monomolecular-dehydrated intermediate 1,4-sorbitan. This was attributed to the selective intercalation of sorbitol within the interlayers with strong Brønsted acid sites. The power of intercalation: The aqueous-phase dehydration of a sugar alcohol, sorbitol, to its monomolecular dehydrated intermediate, 1,4-sorbitan, with high selectivity is described for the use of a unique solid acid, HNbMoO6. The activity and selectivity to 1,4-sorbitan is superior to those obtained on other solid acids, including protonic zeolites, niobic acid, and ion-exchange resins. This improvement is attributable to the control intercalation selectivity.
AB - Layered niobium molybdate (HNbMoO6) was used in the aqueous-phase dehydration of sorbitol and was found to exhibit remarkable selectivity toward its monomolecular-dehydrated intermediate 1,4-sorbitan. This was attributed to the selective intercalation of sorbitol within the interlayers with strong Brønsted acid sites. The power of intercalation: The aqueous-phase dehydration of a sugar alcohol, sorbitol, to its monomolecular dehydrated intermediate, 1,4-sorbitan, with high selectivity is described for the use of a unique solid acid, HNbMoO6. The activity and selectivity to 1,4-sorbitan is superior to those obtained on other solid acids, including protonic zeolites, niobic acid, and ion-exchange resins. This improvement is attributable to the control intercalation selectivity.
UR - http://www.scopus.com/inward/record.url?scp=84896825501&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84896825501&partnerID=8YFLogxK
U2 - 10.1002/cssc.201300946
DO - 10.1002/cssc.201300946
M3 - Article
C2 - 24478140
AN - SCOPUS:84896825501
VL - 7
SP - 748
EP - 752
JO - ChemSusChem
JF - ChemSusChem
SN - 1864-5631
IS - 3
ER -