Intercalation-induced esterification over a layered transition metal oxide

Atsushi Takagaki, Ryo Sasaki, Caio Tagusagawa, Kazunari Domen

Research output: Contribution to journalArticle

23 Citations (Scopus)

Abstract

The layered transition metal oxide HNbMoO6 is demonstrated to catalyze the esterification of lactic acid (a hydroxycarboxylic acid) with activity superior or comparable to conventional ion-exchange resins. Layered HNbMoO6 also catalyzes the esterification of propionic acid (a carboxylic acid) in the presence of lactic acid, despite exhibiting negligible activity for any carboxylic acid as the sole reactant. X-ray diffraction (XRD) measurements indicate that lactic acid is intercalated into the interlayer structure of the oxide whereas carboxylic acid is not. The intercalation mechanism thus greatly affects the catalytic activity of this layered catalyst.

Original languageEnglish
Pages (from-to)592-596
Number of pages5
JournalTopics in Catalysis
Volume52
Issue number6-7
DOIs
Publication statusPublished - Jun 2009
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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