Interfacial tension and wetting behavior of air/oil/ionic liquid systems

Takashi Matsuda, Yu Mishima, Saeid Azizian, Hiroki Matsubara, Takanori Takiue, Makoto Aratono

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

We measured the interfacial tension and the density of air/n-hexane, n-decane, 1-perfluorohexane/1-hexyl-3-methyl-imidazolium hexafluorophosphate systems as a function of temperature. From the air/ionic liquid surface tension values, it was suggested that Coulombic interaction between imidazolium cations and counter anions are not so much different between the surface and bulk. The density values indicated that the decrease of surface tension by saturating organics was closely correlated to the mutual solubility between ionic liquid and organics. Interfacial tension at the oil/ionic liquid interfaces suggested that ionic liquid molecules were more ordered at the oil/ionic liquid interfaces compared to the air/ionic liquid interfaces, but the decrease of the entropy due to the interfacial orientation of ionic liquid was compensated by the increase of the entropy due to the contact of different chemical species. The initial spreading coefficients and the Hamaker constants indicated that all the oil phases spread at the air/ionic liquid interfaces spontaneously, and form the complete wetting films.

Original languageEnglish
Pages (from-to)1601-1605
Number of pages5
JournalColloid and Polymer Science
Volume285
Issue number14
DOIs
Publication statusPublished - Nov 1 2007

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Polymers and Plastics
  • Colloid and Surface Chemistry
  • Materials Chemistry

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