Intermediate temperature CO2 electrolysis by using La0.9Sr0.1Ga0.8Mg0.2O3 oxide ion conductor

Shijing Wang, Tatsumi Ishihara

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

Solid oxide electrolysis cell for electrolysis of CO2 to CO was studied with the cell using LaGaO3-based electrolyte at the intermediate temperature (i.e. 973-1 173 K). Various metal additives to Ni were examined for cathode to CO2 reduction and it was fund that Ni added with Fe shows high activity and the current density of 1.5 A/cm2 was achieved at 1.6 V and 1 073 K on Ni-Fe (9:1) cathode. Improved electrolysis activity was explained by the expanded reaction site which may be assigned the fine particle of Ni. Furthermore, effects of additives to Ni cathode were studied and it was found that the electrolysis current could be much improved by addition of Fe to Ni. Effects of oxide ion conductor mixing with Ni-Fe were further studied and it was found that mixing La0.6Sr0.4Fe0.9Mn0.1O3 with Ni-Fe bimetal is the most effective for achieving high electrolysis current of CO2 of 2.07 A/cm2 at 1.6 V and 1 073 K.

Original languageEnglish
Pages (from-to)381-386
Number of pages6
Journalisij international
Volume55
Issue number2
DOIs
Publication statusPublished - Jan 1 2015

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Electrolysis
Oxides
Ions
Cathodes
Regenerative fuel cells
Bimetals
Temperature
Carbon Monoxide
Electrolytes
Current density
Metals

All Science Journal Classification (ASJC) codes

  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

Cite this

Intermediate temperature CO2 electrolysis by using La0.9Sr0.1Ga0.8Mg0.2O3 oxide ion conductor. / Wang, Shijing; Ishihara, Tatsumi.

In: isij international, Vol. 55, No. 2, 01.01.2015, p. 381-386.

Research output: Contribution to journalArticle

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abstract = "Solid oxide electrolysis cell for electrolysis of CO2 to CO was studied with the cell using LaGaO3-based electrolyte at the intermediate temperature (i.e. 973-1 173 K). Various metal additives to Ni were examined for cathode to CO2 reduction and it was fund that Ni added with Fe shows high activity and the current density of 1.5 A/cm2 was achieved at 1.6 V and 1 073 K on Ni-Fe (9:1) cathode. Improved electrolysis activity was explained by the expanded reaction site which may be assigned the fine particle of Ni. Furthermore, effects of additives to Ni cathode were studied and it was found that the electrolysis current could be much improved by addition of Fe to Ni. Effects of oxide ion conductor mixing with Ni-Fe were further studied and it was found that mixing La0.6Sr0.4Fe0.9Mn0.1O3 with Ni-Fe bimetal is the most effective for achieving high electrolysis current of CO2 of 2.07 A/cm2 at 1.6 V and 1 073 K.",
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