TY - JOUR
T1 - Intermolecular spin-coupler
T2 - Ferromagnetic spin interactions through hydrogen bond in the complexes of arylboronic acids with aryl nitronyl nitroxides
AU - Akita, Takeyuki
AU - Kobayashi, Keiji
N1 - Funding Information:
Financial support by the Grant-in-Aid Scientific Research on Priority Area (No. 06218209 and 06242105) from the Ministry of Education, Science and Culture, Japan, is gratefully acknowledged.
PY - 1997
Y1 - 1997
N2 - Two crystalline complexes, the complex of p-fluorophenylboronic acid with phenyl nitronyl nitroxide (2) and the complex of p-nitrophenylboronic acid with p-dimethylaminophenyl nitronyl nitroxide (3), were prepared. Both of those complexes as well as the complex of phenylboronic acid with phenyl nitronyl nitroxide (1) exhibit ferromagnetic spin interactions (1: J/kB=+0.65 K, 2: J/kB=+0.58 K, 3: J/kB=+1.35 K). The results are discussed based on the X-ray crystal structure.
AB - Two crystalline complexes, the complex of p-fluorophenylboronic acid with phenyl nitronyl nitroxide (2) and the complex of p-nitrophenylboronic acid with p-dimethylaminophenyl nitronyl nitroxide (3), were prepared. Both of those complexes as well as the complex of phenylboronic acid with phenyl nitronyl nitroxide (1) exhibit ferromagnetic spin interactions (1: J/kB=+0.65 K, 2: J/kB=+0.58 K, 3: J/kB=+1.35 K). The results are discussed based on the X-ray crystal structure.
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U2 - 10.1080/10587259708044574
DO - 10.1080/10587259708044574
M3 - Article
AN - SCOPUS:0031337328
SN - 1542-1406
VL - 306
SP - 257
EP - 264
JO - Molecular Crystals and Liquid Crystals
JF - Molecular Crystals and Liquid Crystals
ER -