Intermolecular spin-coupler: Ferromagnetic spin interactions through hydrogen bond in the complexes of arylboronic acids with aryl nitronyl nitroxides

Takeyuki Akita, Keiji Kobayashi

Research output: Contribution to journalArticlepeer-review

7 Citations (Scopus)

Abstract

Two crystalline complexes, the complex of p-fluorophenylboronic acid with phenyl nitronyl nitroxide (2) and the complex of p-nitrophenylboronic acid with p-dimethylaminophenyl nitronyl nitroxide (3), were prepared. Both of those complexes as well as the complex of phenylboronic acid with phenyl nitronyl nitroxide (1) exhibit ferromagnetic spin interactions (1: J/kB=+0.65 K, 2: J/kB=+0.58 K, 3: J/kB=+1.35 K). The results are discussed based on the X-ray crystal structure.

Original languageEnglish
Pages (from-to)257-264
Number of pages8
JournalMolecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volume306
DOIs
Publication statusPublished - Jan 1 1997
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics

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